Is the translational diffusion of organic radicals different from that of closed-shell molecules?

Accounts of Chemical Research

Volumn 33, Issue 10, 2000, Pages 687-694

  Terazima, M ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

FREE RADICAL; HYDROGEN; ORGANIC COMPOUND;

ARTICLE; CHEMICAL REACTION KINETICS; DIFFUSION; DISSOCIATION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; PHOTOCHEMISTRY; REACTION ANALYSIS;

DIFFUSION; FREE RADICALS; HYDROGEN; ORGANIC CHEMICALS;

EID: 0033785811     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar000003g     Document Type: Article

References (48)

1. Diffusion of free radicals as studied by tomography
2. Measuring the diffusion coefficients for radicals in solutions by EPR tomography
3. Diffusion coefficients in anisotropic fluids by ESR imaging of concentration profiles
4. Photochemical space intermittency. A proposal for measuring diffusion coefficients of reactive free radicals
5. Diffusion coefficients of iodine atoms in carbon tetrachloride by photochemical space intermittency
6. Diffusion coefficients of iodine atoms in carbon tetrachloride: A correction
7. Studies on diffusion and diffusion controlled reactions involving alkyl radicals in solution
8. Diffusion studies on the benzyl and cyclohexyl radicals in solution
9. Measurement of the quantum yield of triplet formation and short triplet lifetimes by the transient grating technique
10. Photothermal studies of photophysical and photochemical processes by the transient grating method
11. Energetic and molecular dynamics in solution studied by the third-order nonlinear optical spectroscopies; Transient lens and transient grating
12. Translational diffusion of intermediate species in solutions
13. Coupled wave theory for thick hologram gratings
14. Translational diffusion of a transient radical studied by the transient grating method; pyrazinyl radical in 2-propanol
15. Transient radical diffusion in photoinduced hydrogen abstraction reactions of benzophenone probed by the transient grating method
16. CW and FT time-resolved EPR investigation of the quenching reaction of the 2-hydroxypropan-2-yl radical
17. Radical diffusion measured by the transient grating in a short time scale
18. Comments on 'Diffusion of free radicals in solution; TEMPO, diphenylpicrylhydrazyl and nitrosodisulfonate'
19. Diffusion of free radicals in solution. TEMPO, diphenylpicrylhydrazyl, and nitrosodisulfonate
20. Translational diffusion of transient radicals created by the photo-induced hydrogen abstraction reaction in solution; Anomalous size dependence in the radical diffusion
21. Temperature dependence of diffusion processes of radical intermediates probed by the transient grating method
22. Tracer diffusion in polyatomic liquids III
23. Diffusion of photochemical intermediate radicals in water/ethanol mixed solvents
24. Tracer diffusion in polyatomic liquids
25. Tracer iffusion in polyatomic liquis II
26. Solvent density dependence of translational diffusion of transient radicals in the medium-density region of trifluoromethane and carbon dioxide
27. Translational diffusion process of charged radical; TMPD and its cation radical
28. Dynamics of aggregate formation and translational diffusion of a spiropyran studied by the transient grating method
29. Optical heterodyne detected transient grating for the separation of phase and amplitude gratings
30. Translational diffusion of a transient charge separated species in carbon dioxide and trifluoromethane studied by the transient grating method
31. Diffusion of electrically neutral radicals and anion radicals created by photochemical reactions
32. Diffusion process of the benzyl radical created by photodissociation probed by the transient grating method
33. Persistent triplet carbenes
34. Translational diffusion of a carbene and radicals derived from carbene
35. Translational diffusion of chemically active species; carbenes and carbonyloxides
36. Translational diffusion of chemically stable and reactive radicals in solution
37. Computer simulation and mode coupling theory study of the effects of specific solute-solvent interactions on diffusion: Crossover from a sub-slip to a super-stick limit of diffusion
38. Molecular theory for the effects of specific solute-solvent interaction on the diffusion of a solute particle in a molecular liquid
39. Ab initio molecular orbital theory on intramolecular charge polarization: Effect of hydrogen abstraction on the charge sensitivity of aromatic and nonaromatic species
40. Molecular dynamics simulation with the charge response kernel: Diffusion dynamics of pyrazine and pyrazinyl radical in methanol
41. Diffusion coefficients of paramagnetic species in solution