Fluoride ion-promoted α-ketol rearrangement during unmasking of silyl-protected medium-ring dihydroxy ketones

Advanced Synthesis and Catalysis

Volumn 346, Issue 7, 2004, Pages 713-716

  Hartung, Ryan E ^a   Hilmey, David G ^a   Paquette, Leo A ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

ketols; Desilylation; Fluoride ion; Medium sized rings; MM3 calculations; Rearrangement

Indexed keywords

BASE; CARBONYL DERIVATIVE; FLUORIDE; HEPTANE DERIVATIVE; HYDROXYL GROUP; KETOL; KETONE DERIVATIVE; OCTANE; OXYGEN; SILICON;

ARTICLE; CALCULATION; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DEPROTECTION REACTION; ENERGY; ISOMERIZATION; REACTION ANALYSIS; SILYLATION; STEREOISOMERISM;

EID: 4143069092     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200404002     Document Type: Article

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