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85034464778
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The stereochemical course of this reduction was established on the strength of NOE experiments performed on 13. The key interactions are illustrated here: Formula presented
-
The stereochemical course of this reduction was established on the strength of NOE experiments performed on 13. The key interactions are illustrated here: Formula presented
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85034483817
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The axial disposition of the hydroxyl was clearly evident on the basis of the appearance of the H-2 methine proton as a doublet of doublets (J = 2.6, 2.6 Hz) at δ 3.99. The two small coupling constants arise from neighboring equatorial-equatorial and equatorial-axial spin interactions
-
The axial disposition of the hydroxyl was clearly evident on the basis of the appearance of the H-2 methine proton as a doublet of doublets (J = 2.6, 2.6 Hz) at δ 3.99. The two small coupling constants arise from neighboring equatorial-equatorial and equatorial-axial spin interactions.
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Ph.D. Thesis, University of Kansas, 1993. We thank Professor J. Aubé for making part of this thesis available to us
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(b) Wang, Y. Ph.D. Thesis, University of Kansas, 1993. We thank Professor J. Aubé for making part of this thesis available to us.
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note
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3) ppm 211.9, 68.6, 52.3, 47.8, 38.5, 32.8, 27.7, 21.6.
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48
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0011877743
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85034467951
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A diastereoselectivity of >97:3 represents the perceived detection limit of the instrument
-
A diastereoselectivity of >97:3 represents the perceived detection limit of the instrument.
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60
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0041790137
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85034464602
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Diol 32 was completely unreactive to these conditions
-
Diol 32 was completely unreactive to these conditions.
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For generic experimental details, see ref 9
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For generic experimental details, see ref 9,
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