On the electron spin polarization observed in TREPR experiments involving hydroxyl and sulfate radicals

Molecular Physics

Volumn 105, Issue 15-16, 2007, Pages 2127-2136

  Forbes, M D E ^a   Lebedeva, N V ^a   White, R C ^a   Chen, T K ^a   MacArthur, R ^a   Caregnato, P ^a   Hill, T E ^a  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

Author keywords

CIDEP; EPR; F pairs; Hydroxyl radicals; Sulfate radical anion

Indexed keywords

AMINO ACIDS; DIFFUSION; ELECTRON TRANSITIONS; NEGATIVE IONS; PARAMAGNETIC RESONANCE; POLARIZATION;

F-PAIRS; HYDROXYL RADICALS; IONIC STRUCTURES; SULFATE RADICAL ANIONS;

FREE RADICALS;

EID: 41149134456     PISSN: 00268976     EISSN: 13623028     Source Type: Journal    
DOI: 10.1080/00268970701663768     Document Type: Article

References (37)

1. R. C. White and M. D. E. Forbes, Org. Lett. 8., 6027 (2006).
2. M. C. R. Symons, J. Am. Chem. Soc. 91, 5924 (1969).
3. R. W. Fessenden and R. H. Schuler, J. Chem. Phys. 39, 2147 (1963).
4. M. R. Gunther, B. E. Sturgeon, and R. P. Mason, Free Radic. Biol. Med. 28, 709 (2000).
5. D. A. Svistunenko, Biochim. Biohys. Acta 1707, 127 (2005).
6. T. Simandan, J. Sun, and T. A. Dix, Biochem J. 335, 233 (1998).
7. K. J. A. Davies, J. Biol. Chem. 262, 9895 (1987).
8. L. T. Muus, P. W. Atkins, K. A. McLauchlan, and J. B. Pedersen, Chemically Induced Magnetic Polarization (D. Reidel, Dordrecht, 1977).
9. B. Bhattacharjee and R. Das, Mol. Phys. 105, 1053 (2007).
10. M. D. E. Forbes, Photochem. Photobiol. 65, 73 (1997).
11. A. B. Ross and Farhataziz, Selected Specific Rates of Reactions of Transients from Water in Aqueous Solution, National Standard Reference Data Series, NSRDS -NBS 59 (1977).
12. H. Taniguchi, H. Takagi, and H. Hatano, J. Phys. Chem. 76, 135 (1972).
13. J. R. Woodward, T.-S. Lin, Y. Sakaguchi, and H. Hayashi, J. Phys. Chem. A 104, 557 (2000).
14. -, estimated from low temperature EPR data or room temperature EPR spectra of single crystals, varies between 2.0155 and 2.0303. For a discussion see N. Hariharan and J. Sobhanadri, J. Magn. Resonance 1, 639(1969).
15. P. Tarabek, M. Bonifacic, and D. Beckert, J. Phys. Chem. A 111, 4958 (2007).
16. K. Eiben and R. W. Fessenden, J. Phys. Chem. 75, 1186 (1971).
17. A. D. Trifunac and M. C. Thurnauer, J. Chem. Phys. 62, 4889 (1975).
18. I. Dogan, S. Steenken, D. Schulte-Frohlinde, and S. Icli, J. Phys. Chem. 94, 1887 (1990).
19. K. A. McLauchlan, in Continuous-Wave Transient Electron Spin Resonance, Modern Pulsed and Continuous-Wave Electron Spin Resonance, edited by L. Kevan and M. K. Bowman (Wiley, New York, 1990), p. 285.
20. H. Fischer and H. Paul, Zeitschr. Naturforsch. Teile A, 443(1970).
21. A. D. Trifunac, K. W. Johnson, B. E. Clift, and R. H. Lowers, Chem. Phys. Lett. 35, 566 (1975).
22. For references to the extensive work on the acetone/2-propanol system, see citations 22-29 of [9].
23. K. A. McLauchlan, N. J. K. Simpson, and P. D. Smith, Res. Chem. Intermed. 16, 141 (1991).
24. P. R. Levstein and H. van Willigen, J. Chem. Phys. 95, 900 (1991).
25. G.-H. Goudsmit, F. Jent, and H. Paul, Zeitschr. Phys. Chem. 180, 51 (1993).
26. P. W. Atkins and G. T. Evans, Chem. Phys. Lett. 25, 108 (1974).
27. S. K. Wong, D. A. Hutchinson, and J. K. S. Wan, J. Chem. Phys. 58, 985 (1973).
28. J. A. McMillan, M. S. Matheson, and B. Smaller, J. Chem. Phys. 33, 609 (1960).
29. D. Becker, T. La Vere, and M. D. Sevilla, Radiation Res. 140, 123 (1994).
30. N. C. Verma and R. W. Fessenden, J. Chem. Phys. 65, 2139 (1976).
31. B. Brocklehurst, J. Chem. Soc. Faraday Trans. 75, 123 (1979).
32. F. J. Adrian, J. Chem. Phys. 53, 3374 (1970).
33. F. J. Adrian, J. Chem. Phys. 54, 3912 (1971).
34. 1 values are in the range of 10-100 μs: see J. A. Mucha and D. W. Pratt, J. Chem. Phys. 66, 5356(1977).
35. 1 value for BP, and in fact most other carbonyl triplet states, at 10 ns or less.
36. This parameter is somewhat solvent dependent. For a list of representative values, see Table 1 in M. Okamoto and H. Teranishi, J. Am. Chem. Soc. 108, 6378(1986), and references therein.
37. R. W. Eveson, K. A. McLauchlan, and E. Page-Croft, Mol. Phys. 95, 107 (1998).