Direct synthesis of uniform mesoporous carbons from the carbonization of as-synthesized silica/triblock copolymer nanocomposites

Carbon

Volumn 42, Issue 12-13, 2004, Pages 2711-2719

  Kim, Jaeyun ^a   Lee, Jinwoo ^a   Hyeon, Taeghwan ^a  

^a Seoul National University   (South Korea)

Author keywords

A. Porous carbon; B. Carbonization; BET surface area; C. Electron microscopy

Indexed keywords

BLOCK COPOLYMERS; CARBONIZATION; CATALYSIS; COPOLYMERS; CROSSLINKING; ELECTRON MICROSCOPY; MESOPOROUS MATERIALS; POLYMERIZATION; SILICA; SOL-GELS; SYNTHESIS (CHEMICAL);

ALUMINA MEMBRANES; CARBON PRECURSORS; MICROEMULSION TEMPLATE; POROUS CARBON;

CARBON;

EID: 4043133756     PISSN: 00086223     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbon.2004.06.018     Document Type: Article

References (39)

1. Marsh H, Heintz EA, Rodriguez-Reinoso F. Introduction to carbon technology. Alicante: Universidad de Alicante, Secretariado de Publicationes; 1997.
2. Kinoshita K. Carbons: electrochemical and physicochemical properties. New York: Wiley; 1988.
3. Kyotani T. Control of pore structure in carbon. Carbon 2000;38:269-86.
4. Johnson SA, Brigham ES, Olliver PJ, Mallouk TE. Effect of micropore topology on the structure and properties of zeolite polymer replicas. Chem Mater 1997;9:2448-58.
5. Kyotani T, Nagai T, Inoue S, Tomita A. Formation of new type of porous carbon by carbonization in zeolite nanochannels, Chem Mater 1997;9:609-15.
6. Ma Z, Kyotani T, Tomita A. Preparation of a high surface area microporous carbon having the structural regularity of Y zeolite. Chem Commun 2000:2365-6.
7. Ma ZX, Kyotani T, Liu Z, Terasaki O, Tomita A. Very high surface area microporous carbon with a three-dimensional nano-array structure: synthesis and its molecular structure. Chem Mater 2001;13:4413-5.
8. Kyotani T, Tsai L, Tomita A. Formation of ultrafine carbon tubes by using an anodic aluminum oxide film as a template. Chem Mater 1995;7:1427-8.
9. Kyotani T, Tsai L, Tomita A. Preparation of ultrafine carbon tubes in nanochannels of an anodic aluminum oxide film. Chem Mater 1996;8:2109-13.
10. Che G, Lakshimi BB, Fisher ER, Martin CR. Carbon nanotubule membranes for electrochemical energy storage and production. Nature 1998;393:346-9.
11. Zakhidov AA, Baughman RH, Iqbal Z, Cui C, Khayrullin I, Dantas SO, et al. Carbon structures with three-dimensional periodicity at optical wavelengths. Science 1998;282: 897-901.
12. Han S, Hyeon T. Novel silica-sol mediated synthesis of high surface area porous carbons. Carbon 1999;37:1645-7.
13. Han S, Hyeon T. Simple silica-particle template synthesis of mesoporous carbons. Chem Commun 1999:1955-6.
14. Yu JS, Yoon SB, Chai GS. Ordered uniform porous carbon by carbonization of sugars. Carbon 2001;39:1442-6.
15. Han S, Sohn K, Hyeon T. Fabrication of new nanoporous carbons through silica templates and their application to the adsorption of bulky dyes. Chem Mater 2000;12:3337-41.
16. Lee J, Yoon S, Hyeon T, Oh SM, Kim KB. Synthesis of a new mesoporous carbon and its application to electrochemical double layer capacitors. Chem Commun 1999:2177-8.
17. Lee J, Yoon S, Oh SM, Shin C, Hyeon T. Development of a new mesoporous carbon using an HMS aluminosilicate template. Adv Mater 2000;12:359-62.
18. Lee J, Sohn K, Hyeon T. Fabrication of novel mesocellular carbon foams with uniform ultralarge mesopores. J Am Chem Soc 2001;123:5146-7.
19. Lee J, Sohn K, Hyeon T. Low-cost and facile synthesis of mesoporous carbon foams. Chem Commum 2002:2674-5.
20. Lee J, Han S, Hyeon T. Synthesis of new nanoporous carbon materials using nanostructured silica materials as templates. J Mater Chem 2004;14:478-86.
21. Yoon SB, Sohn K, Kim JY, Shin CH, Yu JS, Hyeon T. Fabrication of carbon capsules with hollow macroporous core/mesoporous shell structures. Adv Mater 2002;14:19-21.
22. Ryoo R, Joo SH, Kruk M, Jaroniec M. Ordered mesoporous carbons. Adv Mater 2001;13:677-81.
23. Ryoo R, Joo SH, Jun S. Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. J Phys Chem B 1999;103:7743-6.
24. Jun S, Joo SH, Ryoo R. Synthesis of new nanoporous carbon with hexagonally ordered mesostructure. J Am Chem Soc 2000;122:10712-3.
25. Lee JS, Joo SH, Ryoo R. Synthesis of naesoporous silicas of controlled pore wall thickness and their replication to ordered nanoporous carbons with various pore diameters. J Am Chem Soc 2002;124:1156-7.
26. Joo SH, Choi SJ, Oh I, Kwak J, Liu Z, Terasaki O, et al. Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles. Nature 2001;412:169-72.
27. Zhang WH, Liang C, Sun H, Shen Z, Guan Y, Ying P, et al. Synthesis of ordered mesoporous carbons composed of nanotubes via catalytic chemical vapor deposition. Adv Mater 2002;14:1776-8.
28. Kim S, Pinnavaia TJ. A low cost route to hexagonal mesostructured carbon molecular sieves. Chem Commun 2001: 2418-9.
29. Yoon SB, Kim JY, Yu JS. Synthesis of highly ordered nanoporous molecular sieves from silylated MCM-48 using divinylbenzene as precursor. Chem Commum 2001:559-60.
30. Yang H, Shi Q, Liu X, Xie S, Jiang. D, Zhang F, et al. Synthesis of ordered mesoporous carbon monoliths with bicontinuous cubic pore structure of Ia3d symmetry. Chem Commun 2002:2842-3.
31. Che S, Carcia-Bennett AE, Liu X, Hodgkins RP, Wright PA, Zhao D, et al. Synthesis of large-pore Ia3d mesoporous silica and its tubelike carbon replica. Angew Chera Int Ed 2003;42:3930-4; Angew. Chem. 2003;115:4060-4.
32. Che S, Carcia-Bennett AE, Liu X, Hodgkins RP, Wright PA, Zhao D, et al. Synthesis of large-pore Ia3d mesoporous silica and its tubelike carbon replica. Angew Chera Int Ed 2003;42:3930-4; Angew. Chem. 2003;115:4060-4.
33. Zhao D, Feng J, Huo Q, Melosh M, Fredirckson GH, Chemlka BF, et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science 1998;279:548-52.
34. Schmidt-Winkel P, Lukens Jr WW, Zhao D, Yang P, Chmelka BF, Stucky GD. J Am Chem Soc 1999;121:254-5.
35. Yoon SB, Kim JY, Yu JS. A direct template synthesis of nanoporous carbons with high mechanical stability using assynthesized MCM-48 hosts. Chem Commum 2002:1536-7.
36. Mastai Y, Polarz S, Antonietti M. Silica-carbon nanocomposites - a new concept for the design of solar absorbers. Adv Funct Mater 2002;12:197-202.
37. Han BH, Zhou W, Sayari A. Direct preparation of nanoporous carbon by nanocasting. J Am Chem Soc 2003;125:3444-5.
38. Kim SS, Lee DK, Shah J, Pinnavaia TJ. Nanocasting of carbon nanotubes: in-situ graphitization of a low-cost mesostructured silica templated non-ionic surfactant micelles. Chem Commun 2003:1436-7.
39. Lin HP, Wong ST, Mou CY, Tang CY. Extensive void defects in mesoporous aluminosilicate MCM-41. J Phys Chem B 2000;104:8967-75.