A spectrophotometric study of iron(III) hydrolysis in aqueous solutions to 200 °C

Chemical Geology

Volumn 249, Issue 1-2, 2008, Pages 227-235

  Stefánsson, Andri ^a   Seward, Terry M ^b  

^a UNIVERSITY OF ICELAND   (Iceland)

^b ETH ZURICH   (Switzerland)

Author keywords

Complexation; Hydrolysis; Hydrothermal; Iron; Spectrophotometry

Indexed keywords

AQUEOUS SOLUTION; COMPLEXATION; ELECTROKINESIS; HYDROCHEMISTRY; HYDROLYSIS; HYDROTHERMAL FLUID; IRON; PRINCIPAL COMPONENT ANALYSIS; SATURATED MEDIUM; SPECTROPHOTOMETRY; VAPOR PRESSURE;

EID: 40249085602     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2007.12.006     Document Type: Article

References (50)

1. Anderson G.M. Castet S. Schott J. Mesmer R.E. The density model for estimation of thermodynamic parameters of reactions at high temperatures and pressures Geochim. Cosmochim. Acta 55 1991 1769 1779
2. Baes C.F. Mesmer R.E. The Hydrolysis of Cations 1976 Krieger Publ. Comp.
3. Bevington P.R. Robinson K. Data Reduction and Error Analysis for the Physical Sciences 1992 McGraw-Hill
4. 2 interactions Geochim. Cosmochim. Acta 69 2005 3773 3789
5. Boily J.-F. Seward T.M. On the dissociation of methyl orange: spectrophotometric investigation in aqueous solutions from 10 to 90 °C and theoretical evidence for intramolecular dihydrogen bonding J. Solid Chem. 34 2005 1387 1406
6. Brubaker G.R. Peterson R.A. Stability of the monochloroiron(III) cation in aqueous solutions between 298 and 398 K Inorg. Chim. Acta 155 1989 139 144
7. Byrne R.H. Kester D.R. Solubility of hydrous ferric oxide and iron speciation in seawater Mar. Chem. 4 1976 255 274
8. Byrne R.H. Kester D.R. Ultraviolet spectroscopic study of ferric hydroxide complexation J. Solid Chem. 7 1978 373 383
9. Byrne R.H. Kester D.R. Ultraviolet spectroscopic study of ferric equilibria at high chloride concentrations J. Solid Chem. 10 1981 51 66
10. Byrne R.H. Luo Y.-R. Young R.W. Iron hydrolysis and solubility revisited: observations and comments on iron hydrolysis characterizations Mar. Chem. 70 2000 23 35
11. Cox J.S. Seward T.M. The hydrothermal reaction kinetics of aspartic acid Geochim. Cosmochim. Acta 71 2007 797 820
12. −(aq) Geochim. Cosmochim. Acta 63 1999 2247 2261
13. Fernandez D.P. Goodwin A.H.R. Lemmon E.W. Sengers J.M.H.L. Williams R.C. A formulation for the static permativity of water and steam at temperatures from 298 K to 873 K at pressures up to 1200 MPa, including derivatives and the Debye–Hueckel coefficients J. Phys. Chem. Ref. Data 26 1997 1125 1166
14. 3+ Ark. Kemi 6 1952 1 16
15. Heinrich C.A. Seward T.M. A spectrophotometric study of aqueous iron(II) chloride complexing from 25 to 200 °C Geochim. Cosmochim. Acta 54 1990 2207–2221
16. Henderson M.P. Miasek V.I. Swaddle T.W. Kinetics of thermal decomposition of aqueous perchloric acid Can. J. Chem. 39 1971 317
17. 2O J. Phys. Chem. Ref. Data 19 1990 1233 1274
18. Ishikawa K. Yoshioka T. Sato T. Okuwaki A. Solubility of hematite in LiOH, NaOH and KOH solutions Hydrometallurgy 45 1997 129 135
19. − 3) J. Chem. Soc. Dalton Trans. 1986 1901 1906
20. Kielland J. Individual activity coefficients of ions in aqueous solutions J. Am. Chem. Soc. 59 1937 1675 1678
21. Knight R.J. Sylva R.N. Spectrophotometric investigation if iron(III) hydrolysis in light and heavy water at 25 °C J. Inorg. Nucl. Chem. 37 1975 779 783
22. Kuma K. Nishioka J. Matsunaga K. Controls on iron(III) hydroxide solubility in seawater: the influence of pH and natural organic chelators Limnol. Oceanogr. 41 1996 396 407
23. Liu X. Millero F.J. The solubility of iron hydroxide in sodium chloride solutions Geochim. Cosmochim. Acta 63 1999 3487 3497
24. Liu W. Etschmann B. Brugger J. Spiccia L. Foran G. McInnes B. Uv–Vis spectrophotometric and XAFS studies of ferric chloride complexes in hyper-saline LiCl solutions at 25–90 °C Chem. Geol. 231 2006 326 349
25. Lopes L. de Laat J. Legube B. Charge transfer of iron(III) monomeric and oligomeric aqua hydroxo complexes: semiempirical investigation into photoactivity Inorg. Chem. 41 2002 2505 2517
26. Mesmer R.E. Marshall W.L. Palmer D.A. Simonson J.M. Holmes H.F. Thermodynamics of aqueous association and ionization reactions at high temperatures and pressures J. Solid Chem. 17 1988 699 718
27. Milburn R.M. A spectrophotometric study of the hydrolysis of iron(III) ion: III. Heat and entropies of hydrolysis J. Am. Chem. Soc. 79 1957 537 540
28. Millero F.J. Yao W. Aicher J.A. The speciation of Fe(II) and Fe(III) in natural waters Mar. Chem. 50 1995 21 39
29. 4 to 373 K and at low pressure: A comprehensive Pitzer ion-interaction model J. Chem. Eng. Data 46 2001 875 884
30. Perera W.N. Hefter G. Mononuclear cyano- and hydroxo-complexes of iron(III) Inorg. Chem. 42 2003 5917 5923
31. Robinson R.A. Stokes R.H. Electrolyte Solutions 1968 Butterworths London
32. Schindler P. Michaelis W. Feitknecht W. Löslichkeitprodukte von Metalloxiden und — hydroxiden. 8. Die Löslichkeit gealterter Eisen(III)-hydroxid-Fällungen Helv. Chim. Acta 46 1963 444 449
33. 3) solubility under hydrothermal conditions Terra Cogn. 8 1988 182
34. 3+ in aqueous solutions Geokhimiya 1999 1218 1229
35. Seward T.M. Equilibrium and oxidation potential in geothermal waters at Broadlands, New Zealand Am. J. Sci. 274 1974 190 192
36. Sharygin A.V. Wood R.H. Volumes and heat capacities of aqueous solutions by hydrochloric acid at temperatures from 298.15 K to 623 K and pressures to 28 MPa J. Chem. Thermodyn. 29 1997 125 148
37. Soli A.L. Byrne R.H. The hydrolysis and fluoride complexation behavior of Fe(III) at 25 °C and 0.68 molal ionic strength J. Solid Chem. 25 1996 773 785
38. Stefánsson A. Iron(III) hydrolysis and solubility at 25 °C Environ. Sci. Technol. 41 2007 6117 6123
39. Stefánsson A. Arnórsson S. Gas pressures and redox reactions in geothermal fluids in Iceland Chem. Geol. 190 2002 251 271
40. Stefánsson A. Gíslason S.R. Arnórsson S. Dissolution of primary minerals in natural waters: II. Mineral saturation state Chem. Geol. 172 2001 251 276
41. Strahm U. Patel R.C. Matijevic E. Thermodynamics and kinetics of aqueous iron(III) chloride complexes formation J. Phys. Chem. 83 1979 1689 1695
42. Suleimenov O.M. Boily J.-F. Pressure dependence of the acid/base equilibrium of methyl orange in aqueous solutions to 1000 bar at 20 °C J. Solid Chem. 35 2006 541 549
43. Sunda W. Huntsman S. Effect of pH, light, and temperature on Fe–EDTA chelation and Fe hydrolysis in seawater Mar. Chem. 84 2003 35 47
44. 3+ and ferric-chloride species Chem. Geol. 162 2000 193 219
45. 2+ in water to 300 °C J. Solid Chem. 9 1980 415 442
46. 3 in dilute aqueous solutions at 300 °C and 10 MPa Sci. Sin. 29 1986 1221 1232
47. Zakaznova-Herzog V.P. Seward T.M. Antimonous acid protonation/deprotonation equilibria in hydrothermal solutions to 300 °C Geochim. Cosmochim. Acta 70 2006 2298 2310
48. Ziemniak S.E. Jones M.E. Combs K.E.S. Magnetite solubility and phase stability in alkaline media at elevated temperatures J. Solid Chem. 24 1995 837 877
49. 3+ at 25–80 °C Geokhimiya 1979 1979 285 290 (in Russian)
50. 3+ion at 80–200 °C Geokhimiya 1980 1980 768 773 (in Russian)