Iron(III) solubility and speciation in aqueous solutions. Experimental study and modelling: Part 1. Hematite solubility from 60 to 300°C in NaOH-NaCl solutions and thermodynamic properties of Fe(OH)4-(aq)

Geochimica et Cosmochimica Acta

Volumn 63, Issue 15, 1999, Pages 2247-2261

  Diakonov, Igor I ^a   Schott, Jacques ^a   Martin, Francois ^a   Harrichourry, Jean Claude ^a   Escalier, Jocelyne ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; HEMATITE; IRON; SOLUBILITY; SPECIATION (CHEMISTRY); THERMODYNAMICS;

EID: 0033371310     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(99)00070-8     Document Type: Article

References (59)

1. Alekseev V.A. Redox potential change rate in the natural solutions (in Russian). Geokhimia. 8/9:1994;1314-1334.
2. Baes C.F., Mesmer R.E. The Hydrolysis of Cations. 1976;Wiley.
3. Baes C.F., Mesmer R.E. The thermodynamics of cation hydrolysis. Am. J. Sci. 281:1981;935-962.
4. Bénézeth P., Diakonov I.I., Pokrovski G.S., Dandurand J.L., Schott J., Khodakovsky I.L. Gallium speciation in aqueous solution. Experimental study and modelling Part 2. Solubility of α-GaOOH in acidic solutions from 150 to 250°C and hydrolysis constants of gallium (III) to 300°C . Geochim. Cosmochim. Acta. 61:1997;1345-1357.
5. Biederman G., Schindler P. On the solubility product of precipitated iron (III) hydroxide. Acta Chem. Scand. 11:1957;731-740.
6. Brookins D.G. Eh-pH Diagrams for Geochemistry. 1988;Springer.
7. Byrne R.H., Kester D.R. Solubility of hydrous ferric oxide and iron speciation in sea water. Mar. Chem. 4:1976;255-274.
8. Castet S., Dandurand J.L., Schott J., Gout R. Boehmite solubility and aqueous speciation in hydrothermal solutions (90-350°C) Experimental study and modelling . Geochim. Cosmochim. Acta. 57:1993;4869-4884.
9. Charlet L. and Manceau L. (1993) Structure, formation, and reactivity of hydrous oxide particles: Insights from X-ray absorption spectroscopy. In Environmental Particles (eds. J. Buffle and H. P. van Leenwen). Lewis Publishers.
10. Diakonov I. (1995) Etude expérimentale de la complexation de l'aluminium avec l'ion sodium et de la spéciation du gallium et du fer (III) dans les solutions naturelles. Ph.D. dissertation, Paul-Sabatier Univ.
11. 3). Eur. J. Miner. 10:1998;17-29.
12. Diakonov I.I. Thermodynamic properties of iron oxides and hydroxides. III. Surface and bulk thermodynamic properties of lepidocrocite (γ-FeOOH) to 500 K. Eur. J. Miner. 10:1998;31-41.
13. 3 species and solubility of iron(III) oxides, hydroxide and hydroxide oxides (in preparation).
14. Diakonov I., Khodakovsky I., Schott J., Sergeeva E. Thermodynamic properties of iron oxides and hydroxides. I. Surface and bulk thermodynamic properties of goethite (α-FeOOH) up to 500 K. Eur. J. Miner. 6:1994;967-983.
15. Diakonov I., Pokrovski G., Castet S., Schott J., Gout R. An experimental and computational study of sodium-aluminum complexing in crustal fluids. Geochim. Cosmochim. Acta. 60:1996;197-211.
16. 4- to 300°C . Geochim. Cosmochim. Acta. 61:1997;1333-1343.
17. Dillenseger C. (1995) Modélisation de la dissolution des oxy-hydroxydes d'aluminium et de fer dans une solution 5 M NaOH à 200 et 250°C. Application au procédé Bayer de traitement de la bauxite. Ph.D. dissertation, Univ. Orléans.
18. Dzombak D.A., Morel F.M.M. Surface Complexation Modelling Hydrous Ferric Oxide . 1990;Wiley.
19. Flynn C.M. Jr. Hydrolysis of inorganic iron (III) salts. Chem. Rev. 84:1984;31-41.
20. Gout R. (1978) Contribution à l'analyse des constituants des bauxites et à l'étude de leurs transformations sous l'effet d'action mécaniques. Thèse d'Etat, Paul-Sabatier Univ.
21. Helgeson H.C., Kirkham D.H., Flowers G.C. Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures IV. Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600°C and 5 kbar . Am. J. Sci. 281:1981;1249-1516.
22. 3, with comments on selected oxygen buffer reactions. Am. Miner. 75:1990;781-790.
23. Ho P., Palmer D.A. Ion association of dilute aqueous sodium hydroxide solutions to 600°C and 300 MPa by conductance measurements. J. Soln. Chem. 25:1996;711-729.
24. Hovey J. K. (1988) Thermodynamics of aqueous solutions. Ph.D. dissertation, Univ. Alberta.
25. 4- from 10 to 55°C . J. Phys. Chem. 92:1988;1323-1332.
26. Johnson J.W., Oelkers E.H., Helgeson H.C. SUPCRT92 A software package for calculating the standard molal properties of minerals, gases, aqueous species and reactions among them from 1 to 5000 bars and 0 to 1000°C . Comp. Geosci. 18:1992;899-947.
27. Kamnev A.A., Ezhov B.B., Malandin O.G., Vasev A.V. The solubility of goethite in basic solutions (in Russian). Zh. Prikl. Khimii. 8:1986;1689-1693.
28. Kuma K., Suzuki Y., Matsunaga K. Solubility and dissolution rate of colloidal γ-FeOOH in seawater. Wat. Res. 27:1993;651-657.
29. 59Fe I. Fällungs- und Auflösungsversuche. Helv. Chim. Acta. 44:1961;796-804.
30. 59Fe II. Der Zustand kleinster Mengen Eisen (III)-hydroxid in wässeriger Lösung. Helv. Chim. Acta. 44:1961;805-811.
31. 3+ ion activities to compute Eh and ferric hydroxide oxide solubilities in anaerobic systems. ACS Symp. Ser. 416:1990;350-367.
32. Martin J.H., et al. Testing the iron hypothesis in ecosystems of the equatorial Pacific Ocean. Nature. 371:1994;123-129.
33. Melnik Y. P. (1972) Thermodynamic Constants for the Analysis of Conditions of Formation of Iron Ores (in Russian). Institute of Geochemistry and Physics of Minerals, Academy of Sciences, Ukraine. 193 p.
34. Melnik Y.P., Drozdovskaya A.A., Vorobyeva K.A., Kalinichenko B.M. New experimental data and calculations of diagenesis of ferrous sediments (in Russian). Geol. Zh. 33:1973;32-41.
35. Millero F.J., Yao W., Aicher J. The speciation of Fe(II) and Fe(III) in natural waters. Mar. Chem. 50:1995;21-39.
36. 2O. Am. Miner. 64:1979;1080-1090.
37. 4 formation on the stability of corundum at high pressures and temperatures. Miner. Mag. 58A:1994;736-737.
38. 2O-NaCl . Am. J. Sci. 295:1996;1255-1342.
39. Pokrovski G., Diakonov I.I., Bénézeth P., Gurevich V., Garvichev K., Gorbunov V., Dandurand J.-L., Schott J., Khodakovsky I. Thermodynamic properties of gallium hydroxide oxide (α-GaOOH) at temperatures to 700 K. Eur. J. Miner. 9:1997;941-951.
40. Robie R.A., Hemingway B.S., Fisher J.R. Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar pressure and at higher temperatures. U.S. Geol. Survey Bull. 1452:1979.
41. Schott J., Berner R.A. Dissolution mechanisms of pyroxenes and olivines during weathering. Drever J.I. The Chemistry of Weathering. 1985;35-53 Reidel.
42. Schwertmann U., Cornell R.M. Iron Oxides in the Laboratory. Preparation and Characterization. 1991;VCH.
43. 3) solubility under hydrothermal conditions. Terra Cognita. 8:1988;182.
44. Shock E.L., Helgeson H.C. Calculation of the thermodynamic and transport properties of aqueous species at high temperatures and pressures Correlation algorithms for ionic species and equation of state predictions to 5 kbar and 1000°C . Geochim. Cosmochim. Acta. 52:1988;2009-2036.
45. Shock E.L., Helgeson H.C., Sverjensky D.A. Calculation of the thermodynamic and transport properties of aqueous species at high temperatures and pressures Standard partial molal properties of inorganic neutral species . Geochim. Cosmochim. Acta. 53:1989;2009-2036.
46. Shock E.L., Oelkers E.H., Johnson J.W., Sverjensky D.A., Helgeson H.C. Calculation of the thermodynamic properties of aqueous species at high pressures and temperatures Effective electrostatic radii, dissociation constants and standard partial molal properties to 1000°C and 5 kbar . J. Chem. Soc. Faraday Trans. 88:1992;803-826.
47. Shock E.L., Sassani D.C., Willis M., Sverjensky D.A. Inorganic species in geologic fluids Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes . Geochim. Cosmochim. Acta. 61:1997;907-950.
48. Shvarov Y. V. (1997) "UT-HEL": A BASIC computer code for calculating the revised HKF equations of state parameters for aqueous species. Version 2-0. Am. Miner. (to be published).
49. Suleimenov O. (1988) The solubility of hematite and the geochemistry of iron in hydrothermal solutions (in Russian). Master's thesis, Moscow State Univ.
50. 3+ (aq) and ferric-chloride species. Chem. Geol., in press.
51. Tanger J.C., Helgeson H.C. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures Revised equation od state for the standard partial properties of ions and electrolytes . Am. J. Sci. 288:1988;19-98.
52. Tremaine P. (1988) Solubility and hydrolysis of aluminum oxides and hydroxides at elevated temperatures from apparent molar heat capacity and volume measurements near 25°C. Proceedings International Conference on Thermodynamics of Aqueous Systems with Industrial Application.
53. 2+ in water to 300°C. J. Soln. Chem. 9:1980;415-442.
54. 2O. Ph.D. dissertation, Paul-Sabatier Univ.
55. Verdes G., Gout R., Castet S. Thermodynamic properties of the aluminate ion and of bayerite, boehmite, diaspore and gibbsite. Eur. J. Miner. 4:1992;767-792.
56. 2O at T = 100-200°C and P up to 9 kbar (in Russian). Geokhimia. 8:1977;1121-1128.
57. Wedepohl K.H. The composition of the continental crust. Geochim. Cosmochim. Acta. 59:1995;1217-1232.
58. 3 in dilute aqueous solutions at 300°C and 10 MPa. Sci. Sinica (Series B). 29:1986;1221-1232.
59. Ziemniak S.E., Jones M.E., Combs K.E.S. Magnetite solubility and phase stability in alkaline media at elevated temperatures. J. Soln. Chem. 24:1995;837-877.