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Volumn 47, Issue 8, 2008, Pages 1465-1468

Incorporation of molybdenum sulfide cluster units into a Dawson-like polyoxometalate structure to give hybrid polythiooxometalates

Author keywords

Arsenic; Hydrothermal synthesis; Molybdenum; Polyoxometalates; Tungsten

Indexed keywords

ARSENIC; HYDROTHERMAL SYNTHESIS; POLYOXOMETALATES; TUNGSTEN;

EID: 39849099575     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704344     Document Type: Article
Times cited : (28)

References (36)
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    • Angew. Chem. Int. Ed. 2005, 44, 3072-3075;
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 3072-3075
  • 20
    • 53549087198 scopus 로고    scopus 로고
    • Diffraction data for 1 and 2 were collected on a Bruker X8 Apex CCD diffractometer with MoKα radiation (λ, 0.71073 Å) by using φ and ω scans of narrow (0.5°) frames at 90.0(2, 1) and 100.0(2) K (2, The structures were solved by direct methods with the SIR2004 program[13] and refined by full-matrix least-squares treatment against, F |2 in anisotropic approximation using the SHELXTL program suite.[14] Absorption corrections were applied empirically using SADABS program [15] for 1 and numerically for 2 using Bruker X8Apex Software.[16] 1: H40AsCs6.50KMo 3N1.50O70S4W15, Mr, 5333.08; 0.09 x 0.05 x 0.02 mm3; triclinic, space group P1, a, 13.0784(2, b, 16.0985(3, c, 20.2299(4) Å, α, 97
    • [17]
  • 22
    • 53549100954 scopus 로고    scopus 로고
    • Bruker, SHELXTL, Version 6.22, Bruker AXS, Inc, Madison, WI, 2003
    • Bruker, SHELXTL, Version 6.22, Bruker AXS, Inc., Madison, WI, 2003.
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    • Program for empirical X-ray absorption correction, Bruker-Nonius
    • G. M. Sheldrick, SADABS, Program for empirical X-ray absorption correction, Bruker-Nonius, 1990.
    • (1990)
    • Sheldrick, G.M.1    SADABS2
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    • 1-2, Bruker
    • Apex2 Software v.2
    • Apex2 Software v.2.1-2, Bruker, 2007.
    • (2007)
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    • 53549111021 scopus 로고    scopus 로고
    • Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax:, 49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository numbers CSD-418320 (1) and -418333 2
    • Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository numbers CSD-418320 (1) and -418333 (2).
  • 29
    • 0037187557 scopus 로고    scopus 로고
    • M. Sokolov, R. Hernandez-Molina, W. Clegg, P. Esparza, A. Mederos, Inorg. Chim. Acta 2002, 331, 25-31,and references cited therein.
    • M. Sokolov, R. Hernandez-Molina, W. Clegg, P. Esparza, A. Mederos, Inorg. Chim. Acta 2002, 331, 25-31,and references cited therein.
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    • 53549124365 scopus 로고    scopus 로고
    • The 183WNMR spectra were obtained on a Bruker MSL300 spectrometer at 12.5 MHz. As external standard an aqueous solution of H 4[SiW12O40] was used to which some Cr 3+ was added, 103.7 ppm, taking the chemical shift of Na 2WO4 in aqueous solution as 0 ppm, Due to low solubility of 1 the NMR experiments were run with sodium salts, which were obtained in the same way by using Na9[AsW9O33] ·13H2O and cluster aqua complexes without introduction of other cations. The products were precipitated with ethanol and redissolved in 2.5 mL of 2M NaCl to give approximately 0.1M concentration of the POM
    • 2O and cluster aqua complexes without introduction of other cations. The products were precipitated with ethanol and redissolved in 2.5 mL of 2M NaCl to give approximately 0.1M concentration of the POM.
  • 34
    • 53549123522 scopus 로고    scopus 로고
    • 2O (C. Tourne, A. Revel, G. Tourne, M. Vendrell, C. R. Acad. Sci. Ser. IIc 1973, 277, 643-645) in 20 mL of water and precipitating with 4.5 g of KCl.
    • 2O (C. Tourne, A. Revel, G. Tourne, M. Vendrell, C. R. Acad. Sci. Ser. IIc 1973, 277, 643-645) in 20 mL of water and precipitating with 4.5 g of KCl.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.