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A plausible mechanism for the cyclopropanation reaction catalyzed with these copper-containing chiral cuboidal clusters could be the heterolytic cleavage of the Cu-S bond, caused by nucleophilic attack of the diazo compound on the copper active center, which is subsequently regenerated after completion of carbene transfer to the alkene. Alternatively, the process may take place through the formation of copper carbene without any substitution or cleavage of the Cu-S bond of the cuboidal clusters; this would result in a penta-coordinated copper(I) ion. Examples of pentacoordinated copper(I)ions have been reported, see: H. Borzel, P. Comba, K. S. Hagen, C. Katsichtis, H. Pritzkow, Chem. Eur. J. 2000, 6, 914.
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