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0003441991
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L. H. Harwood and C. J. Moody, Oxford University Press, Oxford, This regioselective reagent has been recently characterised in solution by NMR spectroscopy and in the solid-state by X-ray crystallographic studies:
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tBu ligand and not its quaternary carbon, hence it can be considered an intramolecular agostic contact. This type of interaction is frequently found in structural organolithium chemistry:
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PMDETA bond distances within 5 [2.132(2), 2.113(2) and 2.196 (2) ] are in the same range as those previously found for this ligand coordinated to lithium in a tridentate fashion, see for example:
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