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We previously reported that 1-phenyltellanyl-1-phenylethane (A) was less efficient for PDI control than corresponding 1-methyltellanyl derivative in styrene polymerization ref 6b, However, the current results suggest that the previous results were affected by unexpected factors presumably a small amount of impurities present in the transfer agent because of the difficulty to obtain pure A
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We previously reported that 1-phenyltellanyl-1-phenylethane (A) was less efficient for PDI control than corresponding 1-methyltellanyl derivative in styrene polymerization (ref 6b). However, the current results suggest that the previous results were affected by unexpected factors presumably a small amount of impurities present in the transfer agent because of the difficulty to obtain pure A.
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d values obtained this study were very small, we do not think that detailed comparison of the substituent effects on the kd is significant.
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d values obtained this study were very small, we do not think that detailed comparison of the substituent effects on the kd is significant.
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