Convenient and efficient access to fluoroalkylated vinylphosphonates via highly regio- and stereoselective hydrometalation or carbometalation reactions of fluorine-containing alkynylphosphonates

Synthesis

Volumn , Issue 4, 2008, Pages 0564-0572

  Konno, Tsutomu ^a   Morigaki, Atsunori ^a   Ninomiya, Kazuo ^a   Miyabe, Tomotsugu ^a   Ishihara, Takashi ^a  

^a KYOTO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Alkynylphosphonates; Carbocupration; Carbozincation; Fluoroalkenes; Hydrostannation; Regioselective; Stereoselective

Indexed keywords

COPPER; LITHIUM; SALTS; STEREOSELECTIVITY;

ALKYNYLPHOSPHONATES; FLUOROALKYLATED VINYLPHOSPHONATES;

FLUORINE;

ALKYL GROUP; ALKYNYL GROUP; ALUMINUM DERIVATIVE; COPPER DERIVATIVE; FLUORINE DERIVATIVE; GRIGNARD REAGENT; ORGANOLITHIUM COMPOUND; PHOSPHONIC ACID DERIVATIVE; VINYL DERIVATIVE; ZINC DERIVATIVE;

ARTICLE; CARBOCUPRATION; CARBOMETALATION; CARBOZINCATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROMETALATION; HYDROSTANNATION; QUANTUM YIELD; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 39749107958     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1032143     Document Type: Article

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