Enhanced solubility of hydrogen in CO2-expanded liquids

Industrial and Engineering Chemistry Research

Volumn 47, Issue 3, 2008, Pages 570-576

  Lopez Castillo, Zulema K ^a   Aki, Sudhir N V K ^a,b   Stadtherr, Mark A ^a   Brennecke, Joan F ^a  

^a University of Notre Dame   (United States)

^b Invista   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ENHANCED SOLUBILITY; EXPANDED LIQUIDS; VAPOR-LIQUID EQUILIBRIUM (VLE);

CARBON DIOXIDE; GAS CHROMATOGRAPHY; METHANOL; PHASE EQUILIBRIA; SOLVENTS; TERNARY SYSTEMS;

HYDROGEN;

CARBON DIOXIDE; GAS CHROMATOGRAPHY; HYDROGEN; METHANOL; PHASE EQUILIBRIA; SOLVENTS; TERNARY SYSTEMS;

EID: 39449117997     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie070105b     Document Type: Article

References (21)

1. 2 expanded methanol solvent system for synthesis of naproxen via enantioselective hydrogenation. J. Supercrit. Fluids 2005, 36, 127-136.
2. 2 Expanded Methanolan Application of Gas Anti-Solvent Reaction (GASR). In Reaction Engineering for Pollution Prevention; Abraham, M. A., Hesketh, R. P., Eds.; Elsevier: Amsterdam, 2000; pp 173-181.
3. Fujita, S.; Akihara, S.; Zhao, F. Y.; Liu, R. X.; Hasegawa, M.; Arai, M. Selective hydrogenation of cinnamaldehyde using ruthenium-phosphine complex catalysts with multiphase reaction systems in and under pressurized carbon dioxide: Significance of pressurization and interfaces for the control of selectivity. J. Catal. 2005, 236, 101-111.
4. Jessop, P. G.; Stanley, R. R.; Brown, R. A.; Eckert, C. A.; Liotta, C. L.; Ngo, T. T.; Pollet, P. Neoteric solvents for asymmetric hydrogenation: supercritical fluids, ionic liquids, and expanded ionic liquids. Green Chem. 2003, 5, 123-128.
5. Solinas, M.; Pfaltz, A.; Cozzi, P. G.; Leitner, W. Enantioselective hydrogenation of imines in ionic liquid/carbon dioxide media. J. Am. Chem. Soc. 2004, 126, 16142-16147.
6. 2-protected amine formation from nitrile and imine hydrogenation in gas-expanded liquids. Ind. Eng. Chem. Res. 2004, 43, 7907-7911.
7. 2-expanded liquids. Ind. Eng. Chem. Res. 2006, 45, 5351-5360.
8. 2 + toluene from 305 to 343 K and 1.2 to 10.5 MPa. Fluid Phase Equilib. 2006, 242, 111-117.
9. Freitag, N. P.; Robinson, D. B. Equilibrium phase properties of the hydrogen-methane-carbon dioxide, hydrogen-carbon dioxide-n-pentane and hydrogen-n-pentane systems. Fluid Phase Equilib. 1986, 31, 183-201.
10. Bezanehtak, K.; Dehghani, F.; Foster, N. R. Vapor-Liquid Equilibrium for the Carbon Dioxide + Hydrogen + Methanol Ternary System. J. Chem. Eng. Data 2004, 49, 430-434.
11. Shenderei, E. R. Z. v.; Ya, D.; Ivanovskii, F. P. Solubility of a carbon dioxide-hydrogen mixture in methanol at low temperatures under pressure. Khim. Prom. 1961, 309-312.
12. BYU. DIPPR 801 Database, 2002.
13. Span, R.; Wagner, W. A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa. J. Phys. Chem. Ref. Data 1996, 25, 1509-1596.
14. Brunner, E. Solubility Of Hydrogen In 10 Organic-Solvents At 298.15-K, 323.15-K, And 373.15-K. J. Chem. Eng. Data 1985, 30, 269-273.
15. Brunner, E.; Hultenschmidt, W.; Schlichtharle, G. Fluid Mixtures at High-Pressures. 4. Isothermal Phase-Equilibria in Binary-Mixtures Consisting of (Methanol + Hydrogen or Nitrogen or Methane or Carbon-Monoxide or Carbon-Dioxide). J. Chem. Thermodyn. 1987, 19, 273-291.
16. Adrian, T.; Wendland, M.; Hasse, H.; Maurer, G. High-pressure multiphase behaviour of ternary systems carbon dioxide water polar solvent: Review and modeling with the Peng-Robinson equation of state. J. Supercrit. Fluids 1998, 12, 185-221.
17. Chang, C. J.; Day, C.-Y.; Ko, C.-M.; Chiu, K.-L. Densities and P-x-y diagrams for carbon dioxide dissolution in methanol, ethanol, and acetone mixtures. Fluid Phase Equilib. 1997, 131, 243-258.
18. Yoon, J. H.; Lee, H. S.; Lee, H. High-Pressure Vapor-Liquid-Equilibria For Carbon-Dioxide Plus Methanol, Carbon-Dioxide Plus Ethanol, And Carbon-Dioxide Plus Methanol Plus Ethanol. J. Chem. Eng. Data 1993, 38, 53-55.
19. Li, X. S.; Englezos, P. Vapor-Liquid Equilibrium of Systems Containing Alcohols Using the Statistical Associating Fluid Theory Equation of State. Ind. Eng. Chem. Res. 2003, 42, 4953-4961.
20. Bezanehtak, K.; Combes, G. B.; Dehghani, F.; Foster, N. R.; Tomasko, D. L. Vapor-liquid equilibrium for binary systems of carbon dioxide plus methanol, hydrogen plus methanol, and hydrogen plus carbon dioxide at high pressures. J. Chem. Eng. Data 2002, 47, 161-168.
21. Ohe, S. Vapor-Liquid Equilibrium Data at High Pressure; Elsevier, Kodansha: Tokyo, 1990; Vol. 42, pp 218-219.