Methylsulfonyl and hydroxyl substituents induce Z-stereocontrol in the McMurry olefination reaction

Synlett

Volumn , Issue 9, 2004, Pages 1513-1516

  Uddin, Md Jashim ^a   Rao, P N Praveen ^a   Knaus, Edward E ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

Acetylation; McMurry olefination; Stereocontrol; Z olefins

Indexed keywords

ALKENE DERIVATIVE; CHLORIDE; FUNCTIONAL GROUP; HYDROXYL GROUP; KETONE DERIVATIVE; MESYLIC ACID DERIVATIVE; TITANIUM DERIVATIVE; ZINC;

ARTICLE; CHEMICAL REACTION; OLEFINATION; STEREOCHEMISTRY;

EID: 3943110188     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-829087     Document Type: Article

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21. 2 (SHELXL-93), giving final agreement factor (R indices) of R1 = 0.0484 and wR2 = 0.1116. Crystallographic data (excluding structure factors) have been deposited at the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 228635. Copies of the data can be obtained free of charge by application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: 44(1223)336033 or e-mail: deposit@ccdc.cam.ac.uk).