Synthesis and molecular structure of hetero-metallic cluster CpCoW(CO)2(S2C2B10 H10)2 and binuclear half-sandwich Co complex [Cp*Co(S2C2B10H10 )]2(bpo) with dichalcogenolate o-carboranyl ligands

Inorganic Chemistry Communications

Volumn 11, Issue 2, 2008, Pages 145-149

  Zhang, Jia Sheng ^a   Jin, Guo Xin ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

Carborane; Cobalt; Dithiolato ligand; Metal metal bonding; Molecular structures

Indexed keywords

EID: 39049132476     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.11.013     Document Type: Article

References (28)

1. Hawthorne M.F., and Zheng Z.P. Acc. Chem. Res. 30 (1997) 267
2. King R.B. J. Organomet. Chem. 692 (2007) 177
3. Valliant J.F., Guenther K.J., King A.S., Morel P., Schaffer P., Sogbein O.O., and Stephenson K.A. Coord. Chem. Rev. 232 (2002) 173
4. Kang Y., Lee J., Kong Y.K., Kang S.O., and Ko J. Organometallics 19 (2000) 1722
5. Crespo O., Gimeno M.C., Jones P.G., and Laguna A. J. Chem. Soc. Chem. Commun. (1993) 1696
6. Herberhold M., Jin G.-X., Yang H., Milius W., and Wrackmeyer B. Eur. J. Inorg. Chem. (1999) 873
7. Herberhold M., Jin G.-X., Yan H., Milius W., and Wrackmeyer B. J. Organomet. Chem. 587 (1999) 252
8. Won J.-H., Kim D.-H., Kim B.Y., Kim S.-J., Lee C., Cho S., Ko J., and Kang S.O. Organometallics 21 (2002) 1443
9. Jin G.-X. Coord. Chem. Rev. 248 (2004) 587
10. Liu S., Han Y.-F., and Jin G.-X. Chem. Soc. Rev. 36 (2007) 1543
11. Wang J.-Q., Ren C.X., and Jin G.-X. Chem. Commun. (2005) 4738
12. Wang J.-Q., Ren C.X., Weng L.-H., and Jin G.-X. Chem. Commun. (2006) 162
13. Wang J.-Q., Ren C.X., and Jin G.-X. Eur. J. Inorg. Chem. (2006) 3274
14. Jin G.-X., Wang J.-Q., Zhang C., Weng L.-H., and Herberhold M. Angew. Chem. Int. Ed. 44 (2005) 259
15. Wang J.-Q., Cai S., Jin G.-X., Weng L.-H., and Herberhold M. Chem. Eur. J. 11 (2005) 7342
16. Wang J.-Q., Herberhold M., and Jin G.X. Organometallics 25 (2006) 3508
17. Wang J.-Q., and Jin G.-X. Inorg. Chem. Commun. 10 (2007) 463
18. Kim D.-H., Ko J., Park K., Cho S., and Kang S.O. Organometallics 18 (1999) 2738
19. Kim B.Y., Lee C., Chung S.W., Lee Y.-J., Pak J., Ko J., and Kang S.O. J. Organomet. Chem. 688 (2003) 236
20. 3, δ/ppm) -7.20, -8.40, -9.95, -11.16 (in the ratio 1:2:1:1)
21. 3, δ/ppm): δ 91.35(s, CS), 102.72 (s, Cp), 211.24 (s, CO).
22. 2 (all data) = 0.0701
23. 2 (all data) = 0.1348
24. 2 by a full-matrix least-squares method. All non-hydrogen atoms were refined with anisotropic thermal parameters. All the hydrogen atoms were included but not refined. All the calculations were carried out with the SHELXTL program [12].
25. Liu S., Zhang J.-S., Wang X., and Jin G.-X. Dalton Trans. (2006) 5225
26. Li W., Weng L.-H., and Jin G.-X. Inorg. Chem. Commun. 7 (2004) 1174
27. Chen Y.-Q., Zhang J.-S., Cai S., Hou X.-F., Schumann H., and Jin G.-X. Dalton Trans. (2007) 749
28. G.M. Sheldrick, SHELXTL-97 Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.