Addition reactions of the novel mononuclear dithio-o-carboranylcobalt(III) complex (η5-C5H5)Co(η2-S 2C2B10H10)

Organometallics

Volumn 18, Issue 15, 1999, Pages 2738-2740

  Kim, Dae Hyun ^a   Ko, Jaejung ^a   Park, Kwonil ^b   Cho, Sungil ^b   Kang, Sang Ook ^a  

^a Korea University   (South Korea)

^b University of Seoul   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000055963     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990269v     Document Type: Article

References (34)

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15. 5).
16. Crystallographic data for 2: a = 11.2866(12) Å, b = 12.677(6) Å, c= 13.2760(19) Å, α = 114.12(3)°, β = 104.985(10)°, and γ = 107.18-(3)° with Z = 2 in space group P1 (No. 2). R1 (wR2) = 0.1751 (0.5016) for 5070 data with I > 2.0σ(I) and anisotropic refinements of the model with idealized hydrogen atoms.
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20. 5).
21. Crystallographic data for 3: a = 15.981(4) Å, b = 55.478(17) Å, c = 12.0562(17) Å, and β = 115.063(16)° with Z = 4 in space group Cc (No. 9). R1 (wR2) = 0.0630 (0.1685) for 9948 data with I > 2.0σ(I) and anisotropic refinements of the model with idealized hydrogen atoms.
22. 2, and the solution was heated ar reflux for 2 h. Addition of hexane to the resulting dark red solution afforded 4a as dark red crystals (0.43 g, 0.91 mmol, 91%). Complexes 4b and 4c were obtained with essentially the same procedure in 87% and 23% yields, respectively.
23. 3).
24. Crystallographic data for 4a: a = 10.0447(7) Å, b = 11.5109(6) Å, c = 12.0399(5) Å, α = 115.980(3)°, β = 106.281(5)°, and γ = 102.960-(5)° with Z = 2 in space group P1 (No. 2). R1 (wR2) = 0.0480 (0.1205) for 4325 data with I > 2.0σ(I) and anisotropic refinements of the model with idealized hydrogen atoms.
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28. 3).
29. Crystallographic data for 5: a = 7.8599(4) Å, b = 9.7306(8) Å, c = 14.7510(7) Å, α = 102.517(5)°, β = 104.820(4)°, and γ = 96.329(5)° with Z = 2 in space group P1 (No. 2). R1 (wR2) = 0.0374 (0.1028) for 4107 data with I > 2.0σ(I) and anisotropic refinements of the model with idealized hydrogen atoms.
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