Metal speciation in natural river waters: Measurement by diffusive gradients in thin-films and estimation by chemical equilibrium model

Japanese Journal of Limnology

Volumn 68, Issue 3, 2007, Pages 391-401

  Nagai, Takashi ^a   Tsunemi, Kiyotaka ^b   Kawamoto, Akemi ^b  

^a NATIONAL INSTITUTE FOR AGRO ENVIRONMENTAL SCIENCES   (Japan)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

Chemical equilibrium model; DGT; Metals; Speciation

Indexed keywords

AQUATIC ORGANISM; BIOAVAILABILITY; CHELATION; CONCENTRATION (COMPOSITION); DATABASE; HEAVY METAL; RIVER WATER; SPECIATION (CHEMISTRY); TOXICITY; WASTEWATER; WATER QUALITY;

ASIA; EURASIA; FAR EAST; JAPAN;

EID: 38849162854     PISSN: 00215104     EISSN: None     Source Type: Journal    
DOI: 10.3739/rikusui.68.391     Document Type: Article

References (34)

1. Allen, H. E. and D. J. Hansen (1996): The importance of trace metal speciation to water quality criteria. Water Environment Research, 68: 42-54.
2. Benedetti, M. F., C. J. Milne, D. G. Kinniburgh, W. H. van Riemsdijk and L. K. Koopal (1995): Metal ion binding to humic substances: Application of the non-ideal competitive adsorption model. Environmental Science and Technology, 29: 446-457.
3. Campbell, P. G. C. (1995): Interactions between trace metals and organisms: critique of the free-ion activity model. In Metal Speciation and Bioavailability in Aquatic Systems, A. Tessier and D. Turner (eds.): 45-102. Wiley.
4. Cleven, R., Nur, Y., Krystek, P. and van Den Berg, G. (2005) Monitoring metal speciation in the rivers Meuse and Rhine using DGT. Water, Air & Soil Pollution, 165: 249-263.
5. Davison, W. and H. Zhang (1994): In situ speciation measurements of trace components in natural waters using thin-film gels. Nature, 367: 546-548.
6. De Schamphelaere, K. A. C., F. M. Vasconcelos, F. M. G. Tack, H. E. Allen and C. R. Janssen (2004): Effect of dissolved organic matter source on acute copper toxicity to Daphnia magna. Environmental Toxicology and Chemistry, 23: 1248-1255.
7. Denney, S., J. Sherwood and J. Leyden (1999): In situ measurements of labile Cu, Cd and Mn in river waters using DGT. Science of the Total Environment, 239: 71-80.
8. DGT Research Ltd., Practical guide for using DGT for metals in waters. http://www.dgtresearch.com.
9. Di Toro, D. M., H. E. Allen, H. L. Bergman, J. S. Meyer, P. R. Paquin and R. C. Santore (2001): Biotic ligand model of the acute toxicity of metals. 1. Technical basis. Environmental Toxicology and Chemistry, 20: 2383-2396.
10. Gimpel, J., H. Zhang, W. Davison and A. C. Edwards (2003): In-situ trace metal speciation in lake surface waters using DGT, dialysis and filtration. Environmental Science and Technology, 37: 138-146.
11. Imai, A., T. Fukushima and K. Matsushige (1999): Effect of iron limitation and aquatic humic substances on the growth of Microcystis aeruginosa. Canadian Journal of Fisheries and Aquatic Sciences, 56: 1929-1937.
12. Imai, A., T. Fukushima, K. Matsushige, Y H. Kim and K. Choi (2002): Characterization of dissolved organic matter in effluents from wastewater treatment plants. Water Research, 36: 859-870.
13. Japanese source.
14. International Network for Acid Prevention (2002): Diffusive gradients in Thin-films (DGT) A technique for determining bioavailable metal concentration. http://www.inap.com.au/public_downloads/ Research_Projects/Diffusive_Gradients_in_Thin-films.pdf
15. Japanese source.
16. Japanese source.
17. Kari, F. G. and W. Giger (1996): Speciation and fate of ethy lenediaminetetraacetate (EDTA) in municipal wastewater treatment. Water Research, 30: 122-134.
18. Kinniburgh, D. G., W. H. van Riemsdijk, L. K. Koopal, M. Borkevec and M. F. Bennedetti (1999): Ion binding to natural organic matter: competition, heterogeneity, stoichiometry and thermodynamic consistency. Colloids and Surfaces A, 151: 147-166.
19. Japanese source.
20. Milne, C. J., D. G. Kinniburgh and E. Tipping (2001): Generic NICA-Donnan parameters for proton binding by humic substances. Environmental Science and Technology, 35: 2049-2059.
21. Milne, C. J., D. G. Kinniburgh, W. H. van Riemsdijk and E. Tipping (2003): Generic NICA-Donnan parameters for metal-ion binding by humic substances. Environmental Science and Technology, 37: 958-971.
22. Martin-Mousset, B., J. P. Croue, E. Lefebvre and B. Legube (1997): Distribution and characterization of dissolved organic carbon of surface waters. Water Research, 31: 541-553.
23. Nowack, B., H. Xue and L. Sigg (1997): Influence of natural and anthropogenic ligands on metal transport during infiltration of river water to groundwater. Environmental Science and Technology, 31: 866-872.
24. Odzak, N, D. Kistler, H. Xue and L. Sigg (2002): In situ trace metal speciation in a eutrophic lake using the technique of diffusion gradients in thin films (DGT). Aquatic Sciences, 64: 292-299.
25. Japanese source.
26. Sarathy, V. and H. E. Allen (2005): Copper complexation by dissolved organic matter from surface water and wastewater effluent. Ecotoxicology and Environmental Safety, 61: 337-344.
27. Sedlak, D. L., J. T. Phinney and W. W. Bedsworth (1997): Strongly complexed Cu and ni in wastewater effluents and surface runoff. Environmental Science and Technology, 31: 3010-3016.
28. Slaveykova, V. I. and K. J. Wilkinson (2005): Predicting the bioavailability of metals and metal complexes: critical review of the biotic ligand model. Environmental Chemistry, 2: 9-24.
29. Tipping, E. (1998): Humic Ion Binding Model VI: An improved description of the interactions of protons and metal ions with humic substances. Aquatic Geochemistry, 4: 3-48.
30. Unsworth, E. R., K. W. Warnken, H. Zhang, W. Davison, F. Black, J. Buffle, J. Cao, R. Cleven, J. Galceran, P. Gunkel, E. Kalis, D. Kistler, H. P. van Leeuwen, M. Martin, S. Noel, Y. Nur, N. Odzak, J. Puy, W. van Riemsdijk, L. Sigg, E. Temminghoff, M. L. Tercier-Waeber, S. Toepperwien, R. M. Town, L. P. Weng and H. B. Xue (2006): Model prediction of metal speciation in freshwaters compared to measurements by in situ techniques. Environmental Science and Technology, 40: 1942-1949.
31. U.S.EPA (2007): Aquatic Life Ambient Freshwater Quality Criteria-Copper 2007 Revision, http://www.epa.gov/waterscience/criteria/copper/2007/ index.htm.
32. Visual MINTEQ, http://www.lwr.kth.se/English/OurSoftware/vminteq/ index.htm.
33. Japanese source.
34. Zhang, H. and W. Davison (1995): Performance characteristics of diffusion gradients in thin films for the in situ measurement of trace metals in aqueous solution. Analytical Chemistry, 67: 3391-3400.