The importance of trace metal speciation to water quality criteria

Water Environment Research

Volumn 68, Issue 1, 1996, Pages 42-54

  Allen, Herbert E ^a   Hansen, David J ^b  

^a UNIVERSITY OF DELAWARE   (United States)

^b U S ENVIRONMENTAL PROTECTION AGENCY   (United States)

Author keywords

copper; criteria; metals; model; speciation; water quality

Indexed keywords

COPPER; TRACE METAL;

ARTICLE; BIOAVAILABILITY; PRIORITY JOURNAL; SUSPENDED PARTICULATE MATTER; TOXICITY TESTING; WATER QUALITY;

EID: 0030046009     PISSN: 10614303     EISSN: None     Source Type: Journal    
DOI: 10.2175/106143096X127307     Document Type: Article

References (45)

1. Allen, H. E. (1993a) The Significance of Trace Metal Speciation for Water, Sediment and Soil Quality Standards. Sci. Total Environ , 134, 23.
2. Allen, H. E. (1993b) Importance of Metal Speciation to Toxicity. Proc. Water Environ. Fed Preconference Seminar Aquatic Life Criteria for Metals, Anaheim, CA, 55.
3. Allen, H. E., Boonlayangoor, C., and Noll, K. E. (1982) Changes in Physicochemical Forms of Lead and Cadmium Added to Freshwater. Environ. Internat., 7, 337.
4. Benson, W. H., Alberts, J., Allen, H. E., Hunt, C. D., and Newman, M. C. (1994) Synopsis of Discussion Session on Bioavailability of Inorganic Elements: In A Mechanistic Understanding of Bioavailabuity: Physical, Chemical, and Biological Interactions. J. L. Hamelink, W. H. Benson, H. L. Bergman, P. F. Landrum (Eds.), Lewis, Boca Raton, Fla., 69-77.
5. Brown, V. M., Shaw, T. L., and Shurben, D. G. (1974) Aspects of Water Quality and the Toxicity of Copper to Rainbow Trout. Water Res. (G.B.), 8, 797.
6. Brungs, W. A., Holderman, T. S., and Southerlan, M. T. (1992) Synopsis of Water-Effect Ratios for Heavy Metals as Derived for Site-Specific Water Quality Criteria. EPA Contract 68-CO-0070, U.S. EPA, Washington, D.C.
7. Buckley, P. J. M., and van den Berg, C. M. G. (1986) Copper Complexation Profiles in the Atlantic Ocean. A Comparative Study Using Electrochemical and Ion Exchange Techniques. Mar. Chem., 19, 281.
8. Cabaniss, S. E., and Shuman, M. S. (1988) Copper Binding by Dissolved Organic Matter: I. Suwannee River Fulvic Acid. Geochim. Cosmochim Acta. 52, 185.
9. Chakoumakos, C., Russo, R. C., and Thurston, R. V. (1979) Toxicity of Copper to Cutthroat Trout (Salmo clarkii) under Different Conditions of Alkalinity, pH, and Hardness. Environ. Sci Technol , 13, 213.
10. Coale, K. H., and Bruland, K. W. (1988) Copper Complexation in the Northeast Pacific. Limnol. Oceanogr , 33, 1084.
11. Cowan, C. E., Jenne, E. A., and Kinnison, R. R. (1986) Methodology for Determining the Relationship between Toxicity and the Aqueous Speciation of a Metal. Aquatic Toxicity and Environmental Fate: Ninth Volume. ASTM STP 921. T. M. Poston and R. Purdy (Eds.) American Society for Testing and Materials, Philadelphia, Pa., 463.
12. 2 Adsorption. M.S. thesis, Illinois Institute of Technology, Chicago, Ill.
13. Ephraim, J., and Marinsky, J. A. (1986) A Unified Physicochemical Description of the Protonation and Metal Ion Complexation Equilibria of Natural Organic Acids (Humic and Fulvic Acids). 3. Influence of Polyelectrolyte Properties and Functional Heterogeneity on the Copper Ion Binding Equilibria in an Armadale Horizons Bh Fulvic Acid Sample. Environ. Sci. Technol., 20, 367.
14. Fish, W., Dzombak, D. A., and Morel, F. M. M. (1986) Metal-humate Interactions. II. Application and Comparison of Models. Environ Sci. Technol., 20, 676.
15. Florence, T. M. (1986) Electrochemical Approaches to Trace Element Speciation in Waters: A Review. Analyst, 111, 489.
16. Hudson, P. V., Borgmann, U., and Shear, H. (1979) Toxicity of Copper to Aquatic Biota: In Copper in the Environment. Part II. Health Effects. J. O. Nriagu (Ed.), Wiley-Interscience, New York, N.Y.
17. Howarth, R. S., and Sprague, J. B. (1978) Copper Lethality to Rainbow Trout in Waters of Various Hardness and pH. Water Res. (G.B.), 12, 455.
18. Kelly, M. (1988) Mining and the Freshwater Environment. Elsevier, Essex, UK.
19. Kramer, C. J. M. (1986) Apparent Copper Complexation Capacity and Conditional Stability Constants in North Atlantic Waters. Mar. Chem., 18, 335.
20. Kramer, C. J. M., and Duinker, J. C. (1984) Measurement of Copper Complexation by Naturally Occurring Ligands. In Complexation of Trace Metals in Natural Waters. C. J. M. Kramer and J. C. Duinker (Eds.) Nijhoff/Junk, The Hague, The Netherlands, 217.
21. Luoma, S. N. (1983) Bioavailability of Trace Metals to Aquatic Organisms - A Review. Sci. Total Environ , 28, 1.
22. Magnuson, W. R., Harriss, D. K., Sun, M. S., Taylor, D. K., and Glass, G. E. (1979) Relationships of Activities of Metal-Ligand Species to Aquatic Toxicity: In Chemical Modeling in Aqueous Systems: Speciation, Sorption, Solubility and Kinetics. E. A. Jenne (Ed.) Symp. Ser. 93. American Chemical Society, Washington, D.C.
23. Meador, J. P. (1991) The Interaction of pH, Dissolved Organic Carbon, and Total Copper in the Determination of Ionic Copper and Toxicity. Aguat. Toxicol., 19, 13.
24. Neubecker, T. A., and Allen, H. E. (1983) The Measurement of Complexation Capacity and Conditional Stability Constants for Ligands in Natural Waters - A Review. Water Res. (G.B.), 17, 1.
25. O'Donnel, J. R., Kaplan, B. M., and Allen, H. E. (1985) Bioavailability of Trace Metals m Natural Waters: In Aquatic Toxicology and Hazard Assessment: Seventh Symposium, American Society for Testing and Materials, Philadelphia, Pa.
26. Pagenkopf, G. K., Russo, R. C., and Thurston, R. V. (1974) Effect of Complexation on Toxicity of Copper to Fishes. J. Fish Res. Bd. Can., 31, 462.
27. Pankow, J. (1991) Aquatic Chemistry Concepts. Lewis, Chelsea, Mich.
28. Perdue, E. M. (1988) Measurements of Binding Site Concentrations in Humic Substances: In Metal Speciation - Theory, Analysis and Application. J. R. Kramer and H. E. Allen (Eds.) Lewis, Chelsea, Mich., 135.
29. Perdue, E. M., and Lytle, C. R. (1983) Distribution Model for Binding of Protons and Metal Ions by Humic Substances. Environ Sci. Technol , 17, 654.
30. Plavsic, M., Krznaric, D., and Branica, M. (1982) Determination of the Apparent Copper Complexing Capacity of Sea Water by Anodic Stripping Voltammetry. Mar. Chem., 11, 17.
31. Prothro, M. G. (1993) Memorandum: Office of Water Policy and Technical Guidance on Interpretation and Implementation of Aquatic Life Metals Criteria. U.S. EPA, Washington, D.C.
32. Robinson, M. G., and Brown, L. N. (1991) Copper Complexation during a Bloom of Gymnodinium sanguineum Hirasaka (Dinophyceae) Measured by ASV. Mar. Chem., 33, 105.
33. Ruzic, I. (1982) Theoretical Aspects of the Direct Titration of Natural Waters and Its Information Yield for Trace Metal Speciation. Anal. Chim Acta, 140, 99.
34. Skrabal, S. A., and Allen, H. E. (1993) Unpublished results.
35. Skrabal, S. A., Luther, G. W., and Allen, H. E. (1992) Chemistry and Bioavailability of Copper in Indian River Bay, Delaware. Final report to Electric Power Partners.
36. Srna, R. F., Garrett, K. S., Miller, S. M., and Thum, A. B. (1980) Copper Complexation Capacity of Marine Water Samples from Southern California. Environ. Sci. Technol., 14, 1482.
37. Stephan, C. E., Mount, D. I., Hansen, D. J., Gentile, J. H., Chapman, G. A., and Brungs, W. A. (1985) Guidelines for Deriving Numerical National Water Quality Criteria for the Protection of Aquatic Organisms and Their Uses. U.S. EPA, Office of Research and Development. PB85-227049. NTIS, Springfield, Va.
38. Stumm, W., and Morgan, J. J. (1981) Aquatic Chemistry. John Wiley and Sons, New York, N.Y.
39. Thursby, G. (1993) Personal communication.
40. Tipping, E., Reddy, M. M., and Hurley, M. A. (1990) Modeling Electrostatic and Heterogeneity Effects on Proton Dissociation from Humic Substances. Environ Sci. Technol., 24, 1700.
41. U.S. EPA (1985) Ambient Water Quality Criteria for Copper - 1984. EPA 440/5-84-031. U.S. EPA, Washington, D.C.
42. U.S. EPA (1986) Quality Criteria for Water 1986. EPA 440/5-86-001. U.S. EPA, Washington, D.C.
43. U.S. EPA (1992) Interim Guidance on Interpretation and Implementation of Aquatic Life Criteria for Metals. U.S. EPA, Washington, D.C.
44. U.S. EPA (1994) Interim Guidance on Determination and Use of Water-Effect Ratios for Metals. EPA 823-B-94-001. U.S. EPA, Washington, D.C.
45. van den Berg, C. M. G., Wong, P. T. S , and Chau, Y. K. (1979) Measurement of Complexing Materials Excreted from Algae and Their Ability to Ameliorate Copper Toxicity. J. Fish. Res. Bd. Can., 36, 901.