The dynamics of morphology development in multiphase latex particles

Progress in Organic Coatings

Volumn 61, Issue 2-4, 2008, Pages 156-165

  Stubbs, Jeffrey M ^a   Sundberg, Donald C ^b  

^a DSM Neoresins ^*  (United States)

^b UNIVERSITY OF NEW HAMPSHIRE   (United States)

Author keywords

Composite; Kinetic; Latex; Morphology; Multi phase; Particle; Thermodynamics

Indexed keywords

COMPOSITE MATERIALS; DECISION TREES; EMULSION POLYMERIZATION; LATEXES; MORPHOLOGY; PHASE SEPARATION; POLYMER BLENDS; THERMODYNAMICS;

COMPOSITE PARTICLES; LATEX BLENDS; MULTIPHASE LATEX PARTICLES; POLYMERIZATION REACTORS;

POLYMER MATRIX;

EID: 38849110776     PISSN: 03009440     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.porgcoat.2007.09.038     Document Type: Article

References (24)

1. Durant Y.G., and Sundberg D.C. Latex particle morphology-fundamental aspects: a review. Polym. React. Eng. 11 3 (2003) 379-432
2. Dimonie V., Daniels E., Schaffer O., and El-Aasser M. Control of particle morphology. In: Lovell P.A., and El-Aasser M.S. (Eds). Emulsion Polymerization and Emulsion Polymers (1997), John Wiley and Sons, Ltd., London pp. 293-326
3. Colombini D., Ljungberg N., Hassander H., and Karlsson O.J. The effect of polymerization route on the amount of interphase in structured latex particles and their corresponding films. Polymer 46 (2005) 1295-1308
4. Heuts M.P.J., le Febre R.A., van Hilst J.L.M., and Overbeek G.C. Influence of morphology on film formation of acrylic coatings. In: Provder T.P., Winnik M., and Urban M. (Eds). Film Formation of Waterborne Coatings. ACS Symposium Series 648 (1996), American Chemical Society, Washington, DC
5. Sundberg D.C., Casassa A.P., Pantazopoulos J., Muscato M.R., Kronberg B., and Berg J. Morphology development of polymeric microparticles in aqueous dispersion. 1. Thermodynamic considerations. J. Appl. Polym. Sci. 41 (1990) 1425
6. Stubbs J., Karlsson O., Jönsson J.-E., Sundberg E., Durant Y., and Sundberg D. Non-equilibrium particle morphology development in seeded emulsion polymerization. 1: penetration of monomer and radicals as a function of monomer feed rate during second stage polymerization. Colloids Surf. A: Physiochem. Eng. Aspects 153 (1999) 255-270
7. de la Cal J., Urzay R., Zamora A., Forcada F., and Asua J. Simulation of the latex particle morphology. J. Polym. Sci. A. Polym. Chem. Ed. 28 (1990) 1031
8. Chern C.-S., and Poehlein G.W. Polymerization in nonuniform latex particles. 1. Distribution of free radicals. J. Polym. Sci., A: Polym. Chem. Ed. 25 (1987) 617-635
9. Chern C.-S., and Poehlein G.W. Polymerization in nonuniform latex particles. 2. Kinetics of two-phase emulsion polymerization. J. Polym. Sci., A: Polym. Chem. Ed. 28 (1990) 3055-3071
10. Krywko W.P., McAuley K.B., and Cunningham M.F. Modelling morphology development in emulsion polymerization. Polym. React. Eng. 10 (2002) 135-162
11. Mills M.F., Gilbert R.G., and Napper D.H. Effect of polymerization kinetics on particle morphology in heterogeneous systems. Macromolecules 23 (1990) 4247-4257
12. Karlsson O.J., Stubbs J.M., Carrier R., and Sundberg D.C. Dynamic modeling of non-equilibrium latex particle morphology development during seeded emulsion polymerization. Polym. React. Eng. 11 4 (2003) 589-625
13. J.M. Stubbs, R. Carrier, D.C. Sundberg, Monte carlo simulation of emulsion polymerization kinetics and the evolution of latex particle morphology and polymer chain architecture, Macromol. Theory Simulation (2007), submitted for publication.
14. Jönsson J.-E., Hassander H., and Törnell B. Polymerization conditions and the development of a core-shell morphology in PMMA/PS latex particles. 1. Influence of initiator properties and mode of monomer addition. Macromolecules 27 (1994) 1932-1937
15. Karlsson L.E., Karlsson O.J., and Sundberg D.C. Nonequilibrium particle morphology development in seeded emulsion polymerization. II. Influence of seed polymer Tg. J. Appl. Polym. Sci. 90 (2003) 905-915
16. Stubbs J.M., and Sundberg D.C. Nonequilibrium particle morphology development in seeded emulsion polymerisation. III. Effect of initiator end groups. J. Appl. Polym. Sci. 91 (2004) 1538-1551
17. Stubbs J.M., and Sundberg D.C. Nonequilibrium particle morphology development in seeded emulsion polymerisation. IV. Influence of chain transfer agent. J. Appl. Polym. Sci. 102 (2006) 945-957
18. Stubbs J.M., and Sundberg D.C. Nonequilibrium particle morphology development in seeded emulsion polymerisation. V. Effect of crosslinking agent. J. Appl. Polym. Sci. 102 (2006) 2043-2054
19. Stubbs J.M., Durant Y.G., and Sundberg D.C. Polymer phase separation in composite latex particles. 1. Considerations for the nucleation and growth mechanism. Comptes Rendus Chimie 6 (2003) 1217-1232
20. Stubbs J.M., and Sundberg D.C. Measuring the extent of phase separation during polymerization of composite latex particles using modulated temperature DSC. J. Polym. Sci. B: Polym. Phys. 43 (2005) 2790-2806
21. Stubbs J.M., and Sundberg D.C. A round robin study for the characterization of latex particle morphology-multiple analytical techniques to probe specific structural features. Polymer 46 (2005) 1125-1138
22. Hourston D.J., Song M., Hammiche A., Pollock H.M., and Reading M. Modulated differential scanning calorimetry. 6: Thermal characterization of multicomponent polymers and interfaces. Polymer 38 (1997) 1-7
23. Swier S., and van Mele B. In situ monitoring of reaction-induced phase separation with modulated temperature DSC: comparison between high-Tg and low-Tg modifiers. Polymer 44 (2003) 6789-6806
24. Fukuhara D., and Sundberg D. The role of carboxylic acid comonomers in morphology control of synthetic latex particles-batch reactions. Progr. Colloid Polym. Sci. 124 (2003) 18-21