Single and double alkyl abstraction from a bis(anilido)xanthene thorium(IV) dibenzyl complex: Isolation of an organothorium cation and a thorium dication

Organometallics

Volumn 27, Issue 1, 2008, Pages 15-17

  Cruz, Carlos A ^a   Emslie, David J H ^a   Harrington, Laura E ^a   Britten, James F ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; COMPLEXATION; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; THORIUM COMPOUNDS;

DIBENZYL COMPLEX; ORGANOTHORIUM CATION; THORIUM DICATIONS;

ORGANOMETALLICS;

EID: 38749134466     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7011503     Document Type: Article

References (43)

1. (a) Hou, Z.; Wakatsuki, Y. Coord. Chem. Rev. 2002, 231, 1.
2. (b) Molander, G. A.; Romero, J. A. C. Chem. Rev. 2002, 102, 2161.
3. (c) Hong, S.; Marks, T. J. Acc. Chem. Res. 2004, 37, 673.
4. (a) Gibson, V. C.; Spitzmesser, S. K. Chem. Rev. 2003, 103, 283.
5. (b) Edelmann, F. T.; Freckmann, D. M. M.; Schumann, H. Chem. Rev. 2002, 102, 1851.
6. (c) Piers, W. E.; Emslie, D. J. H. Coord. Chem. Rev. 2002, 233, 131.
7. (d) Gromada, J.; Carpentier, J.-F.; Mortreux, A. Coord. Chem. Rev. 2004, 248, 397.
8. (e) Arndt, S.; Okuda, J. Adv. Synth. Catal. 2005, 347, 339.
9. (f) Zeimentz, P. M.; Arndt, S.; Elvidge, B. R.; Okuda, J. Chem. Rev. 2006, 106, 2404.
10. (a) Burns, C. J.; Clark, D. L.; Sattelberger, A. P. Actinides: Organometallic Chemistry. In Encyclopedia of Inorganic Chemistry; King, R. B., Lukehart, C. M., Eds.; John Wiley & Sons: Chichester, England, 2005; Vol. 1, p 33.
11. (b) Barnea, E.; Eisen, M. S. Coord. Chem. Rev. 2006, 250, 855.
12. Cruz, C. A.; Emslie, D. J. H.; Harrington, L. E.; Britten, J. F.; Robertson, C. M. Organometallics 2007, 26, 692.
13. (a) Jantunen, K. C.; Batchelor, R. J.; Leznoff, D. B. Organometallics 2004, 23, 2186.
14. (b) Jantunen, K. C.; Haftbaradaran, F.; Katz, M. J.; Batchelor, R. J.; Schatte, G.; Leznoff, D. B. Dalton Trans. 2005, 3083.
15. Keogh, D. W. Actinides: Inorganic & Coordination Chemistry. In Encyclopedia of Inorganic Chemistry; King, R. B., Crabtree, R. H., Eds.; John Wiley & Sons: Chichester, England, 2005; Vol. 1, p 2.
16. For the synthesis of N-mesityl- and N-cyclohexyl-substituted 4,5-bis(amido)xanthene ligands, and the preparation of titanium(IV) bis(amido) and dibenzyl complexes, see: Porter, R. M.; Danopoulos, A. A. Polyhedron 2006, 25, 859.
17. 2 (35.9).
18. (a) Chen, Y.-X.; Marks, T. J. Organometallics 1997, 16, 3649.
19. (b) Horton, A. D.; de With, J. Organometallics 1997, 16, 5424.
20. (c) Pellecchia, C.; Immirzi, A.; Grassi, A.; Zambelli, A. Organometallics 1993, 12, 4473.
21. +, was not observed: Pellecchia, C.; Immirzi, A.; Pappalardo, D.; Peluso, A. Organometallics 1994, 13, 3173.
22. (a) Lin, Z.; Le Marechal, J.-F.; Sabat, M.; Marks, T. J. J. Am. Chem. Soc. 1987, 109, 4127.
23. (b) Yang, X.; Stern, C. L.; Marks, T. J. Organometallics 1991, 10, 840.
24. (c) Yang, X.; King, W. A.; Sabat, M.; Marks, T. J. Organometallics 1993, 12, 4254.
25. (d) Jia, L.; Yang, X.; Stern, C.; Marks, T. J. Organometallics 1994, 13, 3755.
26. (e) Chen, Y.-X.; Stern, C. L.; Yang, S.; Marks, T. J. J. Am. Chem. Soc. 1996, 118, 12451.
27. (f) Jia, L.; Yang, X.; Stern, C. L.; Marks, T. J. Organometallics 1997, 16, 842.
28. (a) Evans, W. J.; Kozimor, S. A.; Ziller, J. W. Organometallics 2005, 24, 3407.
29. 4], has also been reported: Dash, A. K.; Wang, J. X.; Berthet, J.-C.; Ephritikhine, M.; Eisen, M. S. J. Organomet. Chem. 2000, 604, 83.
30. 4): (a) ref 14b.
31. (b) Maynadié, J.; Berthet, J.-C.; Thuéry, P.; Ephritikhine, M. J. Am. Chem. Soc. 2006, 128, 1082.
32. (c) Maynadié, J.; Berthet, J.-C.; Thuéry, P.; Ephritikhine, M. Organometallics 2006, 25, 5603.
33. (a) See for example: Bosch, B. E.; Erker, G.; Fröhlich, R.; Meyer, O. Organometallics 1997, 16, 5449.
34. (b) Cendrowski-Guillaume, S. M.; Lance, M.; Nierlich, M.; Ephritikhine, M. Organometallics 2000, 19, 3257.
35. (c) Arndt, S.; Spaniol, T. P.; Okuda, J. Angew. Chem., Int. Ed. 2003, 42, 5075.
36. (d) Elvidge, B. R.; Arndt, S.; Zeimentz, P. M.; Spaniol, T. P.; Okuda, J. Inorg. Chem. 2005, 44, 6777.
37. (e) Bambirra, S.; Meetsma, A.; Hessen, B. Organometallics 2006, 25, 3454.
38. (f) reference 2e.
39. Guérin, F.; Stephan, D. W. Angew. Chem., Int. Ed. 2000, 39, 1298.
40. 2.
41. Green, M. L. H.; Sassmannshausen, J. Chem. Commun. 1999, 115.
42. Ward, B. D.; Bellemin-Laponnaz, S.; Gade, L. H. Angew. Chem., Int. Ed. 2005, 44, 1668.
43. Tredget, C. S.; Bonnet, F.; Cowley, A. R.; Mountford, P. Chem. Commun. 2005, 3301.