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Volumn 8, Issue 1, 2008, Pages 172-175

Metal-ligand directed assembly of layered cluster-based coordination polymer and its solvent-mediated structural transformations

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EID: 38449088917     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg070532s     Document Type: Article
Times cited : (39)

References (28)
  • 22
    • 84868424933 scopus 로고    scopus 로고
    • Mn(salen)(H2O)]2[(Mn(salen, 2(Nb6Cl12(CN)6)}·0. 66MeOH·5.33H2O (2, The mixing of [Mn(salen, ClO4 (10.0 mL, 12.0 mM) in MeOH and (Me4N) 4[Nb6Cl12(CN)6, 10.0 ml, 4.0 mM) in H2O lead to the formation of brown microcrystalline precipitate immediately. The solid was collected by centrifugation washed with MeOH then dried under vacuum (Yield: 18.7 mg, 25, Anal. Calc. For C 70.67H73.33 Cl12Mn4N 14Nb6O16: C, 32.93; H, 2.87, Found: C, 32.73; H, 2.70, νCN, 2131 cm-1. Green-brown crystals suitable for X-ray analysis were obtained by layering method, Et 4N)2{[Mn(salen, H2O, 2Nb6Cl12(CN)6}·6H 2
    • -1.
  • 23
    • 84868424934 scopus 로고    scopus 로고
    • Crystal data for 2: monoclinic, space group P2(1)/c, a, 14.949(4, b, 13.373(4, c, 22.736(6) Å, β= 94.409(4)°, V, 4532(2) Å3 at T, 193(2) K, Z, 2, Dcalcd, 1.889 g cm-3, R1(wR 2, 0.0473(0.1028, Crystal data for 3: monoclinic, space group P2(1)/c, a, 13.381(2, b, 20.966(4, c, 13.915(2) Å, β= 91.546(3)°, V, 3902.4(12) Å3 at T, 193(2) K, Z, 2, Dcalcd, 1.830 g cm-3, R1 (wR2, 0.0713 (0.1534).Crystal data for 4: orthorhombic, space group Pbcn, a, 21.822(4, b, 17.499(3, c, 29.117(6) Å, V, 11118(4) Å3 at T, 193(2) K, Z, 4, D calcd, 1.824 g cm-3, R1(wR 2, 0.04700.0989
    • 2)= 0.0470(0.0989).
  • 28
    • 38449085992 scopus 로고    scopus 로고
    • Spek, A. L. PLATON, Version 1.62; University of Utrecht, 1999
    • Spek, A. L. PLATON, Version 1.62; University of Utrecht, 1999.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.