Photochemical rearrangement of a rhenium dimetallacyclobutene studied by time-resolved infrared spectroscopy

Organometallics

Volumn 15, Issue 9, 1996, Pages 2189-2191

  Casey, Charles P ^a   Boese, William T ^b   Cariño, Ronald S ^a   Ford, Peter C ^b  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 3843068942     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960015z     Document Type: Article

References (18)

1. (a) Poliakoff, M.; Weitz, E. Adv. Organomet. Chem. 1986, 25, 277-316.
2. (b) DiBenedetto, J. A.; Ryba, D. W.; Ford, P. C. Inorg. Chem. 1989, 28, 3503.
3. (c) Weiller, B. H.; Wasserman, E. P.; Bergman, R. G.; Moore, C. B.; Pimentel, G. C. J. Am. Chem. Soc. 1989, 111, 8288-8289.
4. (d) Belt, S. T.; Ryba, D. W.; Ford, P. C. J. Am. Chem. Soc. 1991, 113, 9524-9528.
5. (e) Boese, W. T.; Lee, B. L.; Ryba, D. W.; Belt, S. T.; Ford, P. C. Organometallics 1993, 12, 4739-4741.
6. Casey, C. P.; Cariño, R. S.; Hayashi, R. K.; Schladetzky, K. D. J. Am. Chem. Soc. 1996, 118, 1617-1623.
7. 1d (4) Qualitative studies using a Rayonette photoreactor with maximum emission ∼300 nm indicated that the relative efficiency of the 2 → 3 conversion in benzene is higher than indicated in the present case. This would be expected given the common feature observed in metal carbonyl cluster chemistry that shorter wavelength irradiation leads to higher quantum yields of CO labilization.
8. (a) Boese, W. T.; Ford, P. C. Organometallics 1994, 13, 3525-3531.
9. (b) Boese, W. T.; Ford, P. C. J. Am. Chem. Soc. 1995, 117, 8381-8391.
10. (a) Ford, P. C.; Boese, W.; Lee, B.; McFarlane, K. In Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds Kalyanasundaram, K., Graetzel, M., Eds.; Kluwer Academic: Dordrecht, The Netherlands, 1993; Chapter 12, pp 359-390.
11. (b) Kobayashi, T.; Yasufuku, K.; Iwa, J. Yesaka, H.; Noda, H.; Ohtani, H. Coord. Chem. Rev. 1985, 64, 1-19.
12. (c) Geoffroy, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979.
13. Casey, C. P.; Ha, Y.; Powell, D. R. J. Am. Chem. Soc. 1994, 116, 3424.
14. Casey, C. P.; Cariño, R. S.; Sakaba, H. Manuscript in preparation.
15. Casey, C. P.; Cariño, R. S. Unpublished results.
16. Casey, C. P.; Sakaba, H.; Hazin, P. N.; Powell, D. R. J. Am. Chem. Soc. 1991, 113, 8165.
17. -1) have similar CO stretching frequencies: Milke, J.; Missling, C.; Sunkel, K.; Beck, W. J. Organomet. Chem. 1993, 445, 219.
18. Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc. 1990, 112, 3713.