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The activation energy for the β C-H scission b n•/zn• → bn/zn, H• (Scheme 1b) is ∼200 kJ/mol, while that for the β C-C bond scission b n•/zn• → bn-1•/zn-1 •, C8H8 (monomer loss) is ∼80 kJ/mol; dissociation of bn•/zn • via backbiting and subsequent β C-C bond scission to yield bn-3•/zn-3 •, an-2/yn-2, K3, or J2• (Scheme 1c) also requires ∼80 kJ/mol.17 The activation energies for the competitive β scissions an•/yn
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Note that ana, viz. silverated C4H 9-[CH2C(CH3, Ph)]n-1-CH 2C(Ph)=CH2, and bn, viz. silverated C4H9-[CH2C(CH3)(Ph, n-1-CH=C(CH3)Ph, are isomers and appear at the same m/z values. This is also true for yna, and z n
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