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Volumn 26, Issue 26, 2007, Pages 6586-6590

Bis(imido) W(VI) complexes chelated by N,N′-disubstituted 1,8-diamidonaphthalene: An analysis of bonding, isocyanate insertion, and Al-Me transfer

Author keywords

[No Author keywords available]

Indexed keywords

DIAMIDONAPHTHALENE; ISOCYANATE INSERTION; NONPLANAR COORDINATION; X-RAY STRUCTURE;

EID: 38049172586     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700763v     Document Type: Article
Times cited : (9)

References (49)
  • 1
    • 0036758622 scopus 로고    scopus 로고
    • For recent reviews of β-diketiminates and their metal complexes, see
    • (a) For recent reviews of β-diketiminates and their metal complexes, see: Bourget-Merle, L.; Lappert, M. F.; Severn, J. R. Chem. Rev. 2002, 102, 3031.
    • (2002) Chem. Rev , vol.102 , pp. 3031
    • Bourget-Merle, L.1    Lappert, M.F.2    Severn, J.R.3
  • 8
    • 0034740397 scopus 로고    scopus 로고
    • 2-, see: (a) Danièle, S.; Drost, C.; Gehrhus, B.; Hawkins, S. M.; Hitchcock, P. B.; Lappert, M. F.; Merle, P. G.; Bott, S. G. J. Chem. Soc., Dalton Trans. 2001, 3179.
    • 2-, see: (a) Danièle, S.; Drost, C.; Gehrhus, B.; Hawkins, S. M.; Hitchcock, P. B.; Lappert, M. F.; Merle, P. G.; Bott, S. G. J. Chem. Soc., Dalton Trans. 2001, 3179.
  • 13
    • 33749862619 scopus 로고    scopus 로고
    • An example of a W(VI) β-diketiminate complex can be found in: Tonzetich, Z. J, Jiang, A. J, Schrock, R. R, Müller, P. Organometallics 2006, 25, 4725
    • An example of a W(VI) β-diketiminate complex can be found in: Tonzetich, Z. J.; Jiang, A. J.; Schrock, R. R.; Müller, P. Organometallics 2006, 25, 4725.
  • 26
    • 38049147345 scopus 로고    scopus 로고
    • For simplicity, discussion has been limited to only one of the two independent units of 1 in the unit cell. There are no significant differences in the bond lengths and angles between these two species.
    • For simplicity, discussion has been limited to only one of the two independent units of 1 in the unit cell. There are no significant differences in the bond lengths and angles between these two species.
  • 27
    • 38049154490 scopus 로고    scopus 로고
    • 3, Z = 2, final R indices [I > 2σ(I)] R1 = 0.0270, wR2 = 0.0736.
    • 3, Z = 2, final R indices [I > 2σ(I)] R1 = 0.0270, wR2 = 0.0736.
  • 32
    • 38049167944 scopus 로고    scopus 로고
    • Frisch, M. J.,et al. Gaussian 03, Revision D.01, Gaussian, Inc.: Wallingford, CT, 2004.
    • Frisch, M. J.,et al. Gaussian 03, Revision D.01, Gaussian, Inc.: Wallingford, CT, 2004.
  • 36
    • 38049149492 scopus 로고    scopus 로고
    • These results are summarized in Figures S3-S5 that are provided in the Supporting Information.
    • These results are summarized in Figures S3-S5 that are provided in the Supporting Information.
  • 43
    • 38049163268 scopus 로고    scopus 로고
    • Computational details for the ureato products can be found in the Supporting Information
    • Computational details for the ureato products can be found in the Supporting Information.
  • 44
    • 38049183561 scopus 로고    scopus 로고
    • The structures of 3a and 3b are analogous and discussion will be limited to that of 3b. A thermal ellipsoid plot for 3a as well as the CIF file for this structure can be found in the Supporting Information. The structures of 4a and 4b are analogous and discussion will be limited to that of 4a. A thermal ellipsoid plot for 4b as well as the cif file for this structure can be found in the Supporting Information.
    • The structures of 3a and 3b are analogous and discussion will be limited to that of 3b. A thermal ellipsoid plot for 3a as well as the CIF file for this structure can be found in the Supporting Information. The structures of 4a and 4b are analogous and discussion will be limited to that of 4a. A thermal ellipsoid plot for 4b as well as the cif file for this structure can be found in the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.