Heteronuclear chains of four metal atoms including one quadruply bonded dimetal unit. Dichromium and dimolybdenum compounds with appended copper(I) atoms

Inorganic Chemistry

Volumn 39, Issue 8, 2000, Pages 1743-1747

  Cotton, F Albert ^a   Murillo, Carlos A ^a,b   Roy, Lindsay E ^a   Zhou, Hong Cai ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b UNIVERSIDAD DE COSTA RICA   (Costa Rica)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; COPPER; MOLYBDENUM COMPLEX; PIPERIDINE DERIVATIVE;

ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; LIGAND BINDING; MOLECULAR INTERACTION;

EID: 0034678253     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic991274u     Document Type: Article

References (16)

1. Cotton, F. A.; Daniels, L. M.; Lu, T.; Murillo, C. A.; Wang, X. J. Chem. Soc., Dalton Trans. 1999, 517.
2. Lai, S.-Y.; Lin, T.-W.; Chen, Y.-H.; Wang, C-C.; Lee, G.-H.; Yang, M.-H.; Leung, M-K.; Peng, S.-M. J. Am. Chem. Soc. 1999, 121, 250.
3. Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Pascual, I. Inorg. Chem. Commun. 1998, 1, 1.
4. (a) Mashima, K.; Fukumoto, A.; Nakano, H.; Kaneda, Y.; Tani, K.; Nakamura, A. J. Am. Chem. Soc. 1998, 120, 12151.
5. (b) Mashima, K.; Nakano, H.; Nakamura, A. J. Am. Chem. Soc. 1996, 118, 9803.
6. (c) Mashima, K.; Nakano, H.; Nakamura, A. J. Am. Chem. Soc. 1993, 115, 11632.
7. Mashima, K.; Tanaka, M.; Tani, K. J. Am. Chem. Soc. 1997, 119, 4307.
8. Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Pascual, I.; Zhou, H.-C. J. Am. Chem. Soc. 1999, 121, 6856.
9. 2 converges to R1 = 0.039, wR2 = 0.099 (all data). The structure corresponds to a typical paddlewheel with four bridging ligands; two DPhIP ions are trans to each other with a hanging arm at each end of the Mo-Mo bond. The Mo-Mo distance is 2.0888(7) Å.
10. Cotton, F. A.; Walton, R. A. Multiple Bonds Between Metal Atoms, 2nd ed.; Oxford University Press: New York, 1993.
11. Cotton, F. A.; Murillo, C. A.; Zhou, H.-C. Inorg. Chem., submitted.
12. Cotton, F. A.; Koch, S. A.; Millar, M. Inorg. Chem. 1978, 17, 2014.
13. Cotton, F. A.; Feng, X.; Kibala, P. A.; Matusz, M. J. Am. Chem. Soc. 1988, 110, 2807.
14. Cotton, F. A.; Murillo, C. A.; Lei, P.; Wang, X. Unpublished results.
15. Cotton, F. A.; Murillo, C. A.; Zhou, H.-C. Unpublished results.
16. 3. Data were collected at 213(2) K on a FAST area detector system.