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The CV was baseline corrected by subtraction of a background CV obtained with uncomplexed 2,9-Me2-phen adsorbed onto an EPG electrode. Manually setting a baseline by visual inspection yielded similar results.
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The CV was baseline corrected by subtraction of a background CV obtained with uncomplexed 2,9-Me2-phen adsorbed onto an EPG electrode. Manually setting a baseline by visual inspection yielded similar results.
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23
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38049155467
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2 delivery to the electrode was achieved by rotating the electrode at 100 rpm. This is explored in more detail later to quantify kinetic currents.
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2 delivery to the electrode was achieved by rotating the electrode at 100 rpm. This is explored in more detail later to quantify kinetic currents.
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24
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38049138196
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The kinetic current due to O2 reduction to H2O 2 at -150 mV vs NHE at a 0.195 cm2 electrode in a standard pH 4.8, 20 mM AcO-/20 mM AcOH buffer solution was determined from a Koutecky-Levich analysis to be -26 μA. Upon adsorption of ca. 5 x 10 -10 mol/cm2 of Cu(phen) to the same electrode, the resulting kinetic current due to O2 reduction to H2O was determined to be -347 μA, so the kinetic current due to O2 reduction to H2O2 was ca. 8, Similarly, Anson and colleagues reported less than 6% peroxide generation at -60 mV vs. NHE and fast rotations rates at EPG electrodes with adsorbed Cuphen, ref 8
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2 was ca. 8%. Similarly, Anson and colleagues reported less than 6% peroxide generation at -60 mV vs. NHE and fast rotations rates at EPG electrodes with adsorbed Cu(phen) (ref 8).
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28
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84907999643
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4 was calculated to be 0.23 mM from reported solubility parameters (Battino, R.; Rettich, T. R.; Tominaga, T. J.; Phys. Chem. Ref. Data 1983, 12, 163-178.)
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4 was calculated to be 0.23 mM from reported solubility parameters (Battino, R.; Rettich, T. R.; Tominaga, T. J.; Phys. Chem. Ref. Data 1983, 12, 163-178.)
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