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Crystallographic data: trans-2: C28H 28B4N2, 173 K, 0.20 x 0.20 x 0.08 mm, monoclinic, space group P21/n, a, 14.1990(10, b, 6.0800(2, c, 14.6470(11) Å, β, 103.012(3)°, V, 1232.01(13) Å3, Z, 2, ρcalcd, 1.175 g cm-3, 3.64 ≤ θ ≤ 27.42°, R 1, 0.0502 (I > 2σ(I, wR2, 0.1296 (all data, residual electron density 0.203/-0.172 e Å-3. 3(tmeda)2: C20H 29B2KN3, 173 K, 0.16 x 0.08 x 0.06 mm, triclinic, space group P1, a, 7.4770(5, b, 11.9330(9, c, 12.3420(10) Å, α, 94.030(3, γ, 97.951(4, β, 101.459(5)°, V, 1063.43(14) Å3, Z, 2, ρcalcd, 1.162 g cm-3
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