Hydrogenation of sunflower oil over bimetallic supported catalysts on mesostructured silica material

International Journal of Chemical Reactor Engineering

Volumn 5, Issue , 2007, Pages

  Belkacemi, Khaled ^a   Kemache, Nassima ^a   Hamoudi, Safia ^a   Arul, Joseph ^a  

^a UNIVERSITÉ LAVAL   (Canada)

Author keywords

Activity; Bimetallic catalysts; Hydrog nation; Nano structured support; Saturated fatty acids; Selectivity; Sunflower oil; Trans fatty acids

Indexed keywords

BIMETALS; CATALYSTS; FATTY ACIDS; HYDROGENATION; ISOMERIZATION; NANOSTRUCTURED MATERIALS; SILICA;

BIMETALLIC CATALYSTS; NANO STRUCTURED SUPPORT; SATURATED FATTY ACIDS; SUNFLOWER OIL; TRANS FATTY ACIDS;

VEGETABLE OILS;

EID: 38049086857     PISSN: 21945748     EISSN: 15426580     Source Type: Journal    
DOI: 10.2202/1542-6580.1528     Document Type: Article

References (63)

1. Aduriz, H.R., Gigola, C.E., Sica, A.M., Volpe, M.A., Touroude, R., "Preparation and characterization of Pd-Pb catalysts for selective hydrogenation", Catal. Today, Vol 15, 459-467 (1992).
2. Aduriz, H.R., Bodnariuk, P., Coq, B., Figueras, F., "Alumina- Supported Bimetallic of Palladium Alloyed with Germanium, Tin, Lead, or Antimony from Organometallic precursors. 1-Gas Phase Hydrogenation of 2- Methyl-1-Buten-3-yne (Valylene) and - Methyl -1,3- Butadiene (Isoprene)", J. Catal., Vol 129, 47-57 (1991).
3. Allen, R., Formo, M., Krishnamurthy, R., McDermott, G., Norris F., Sonntag, N., "Bailey's Industrial Oil and Fat Products", vol. 2, fourth ed., eds. D. Swern, John Wiley and Sons, (1982).
4. Andersson, K., Hell, M., Löwendahl, L., Schöön, N.-H., "Diffusivities of Hydrogen and Glyceryl Trioleate in Cottonseed Ooil at Elevated Temperature", J. Am. Oil Chem. Soc., Vol 51, 171-173 (1974).
5. AOCS, "Iodine Value Standard Method", Cd 1C-95 (1994).
6. Ascherio, A, Katan, M. B., Zock, P. L., Stampfer, M. J., Willett, W. C., "Trans fatty acids and coronary heart disease", N. Engl. J. Med., Vol 340, 1994-1998 (1999).
7. Barrett, E. P., Joyner, L. G., Halenda, P. P., "The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms", J. Am. Chem. Soc., Vol 73, 373 (1951).
8. Beenackers, A.A.C.M., Van Swaaij, P.M., "Mass Transfer in Gas-Liquid Slurry Reactors", Chem. Eng. Sci., Vol 48 3109-3139 (1993).
9. Belkacemi, K, Boulmerka, A, Aral, J, Hamoudi, S., "Hydrogenation of vegetable oils with minimum trans and saturated fatty acid formation over a new generation of Pd-catalyst", Topics in Catalysis, Vol 37, 113-120 (2006a).
10. Belkacemi, K, Boulmerka, A, Hamoudi, S, Aral, J, "Activity and selectivity of novel structured Pd-catalysts: Kinetics modeling of vegetable oils hydrogenation", Int. J. Chem. React. Eng., Vol 3, (2006b).
11. Bern, L., Hell, M., Schöön, N-H., "Kinetics of Hydrogenation of Rapeseed Oil. 1. Influence of Transport Steps in Kinetic Study", J. Am. Oil Chem. Soc. Vol 52, 182-187 (1975).
12. Boitiaux, J.P., Cozyns, J., Derrien, M., Leger, G., "Newest Hydrogenation Catalysts, Hydrocarbon Process", Vol 64, 51-59 (1985)
13. Bond, G.C., Rawle, A.F., "Catalytic hydrogenation in the liquid phase. 1. Hydrogenation of Isoprene Catalysed by Palladium, Palladium-Gold and Palladium-Silver Catalysts", J. Mol. Catal., Vol A 109, 261-271 (1996).
14. Briggs, D., Seah, M.P., "Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy", Wiley, New York, p. 503 (1984).
15. Carley, A.F., Chalker, P.R., Roberts, M.W., "Defects in Oxide Overlayers at Nickel Single-Crystal Surfaces", Proc. R. Soc. London, Ser. A Vol 399, 167-179 (1985).
16. Cecchi, G., Castano, J., Ucciani, E., "Catalyse par les métaux précieux en lipochimie. I- Hydrogénation de l'huile de soja catalysée par les métaux précieux supportés". Revue française des Corps Gras, Vol 26, 391-397 (1979).
17. Cerveny, L., Paseka, I., Surma, K., Thanh, N.T., Ruzicka, V., "Competitive Hydrogenation of Unsaturated-Hydrocarbons on Palladium Catalysts Modified with Lead and Thallium", Collect. Czech. Chem. Commun., Vol 50 61-70 (1985).
18. Choi, S.H., Lee, J.S., "XAFS Study of Tin Modification of Supported Palladium Catalyst for 1,3-Butadiene Hydrogenation in the Presence of 1-Butene", J. Catal., Vol 193, 176-185 (2000).
19. Coenen, J.W.E., "Hydrogenation of Edible Oils", J. Am. Oil Chem. Soc., Vol 3, 382-389 (1976).
20. 2 Catalysts by Gas Phase O-Xylene Hydrogenation", J. Molec Catal. A: Chemical, Vol 96, 155-161 (1995)
21. Cordova, W. A., Harriott, P., Mass-Transfer Resistances in Palladium-Catalyzed Hydrogenation of Methyl Linoleate, Chem. Eng. Sci. Vol 30, 1201-1206 (1975).
22. Deroanne, C, "L'analyse calorimétrique différentielle, son intérêt pratique pour le fractionnement de l'huile de palme et la détermination de la teneur en phase solide", Lebensmittel-Wissenschaft & Technologie, Vol 10, 251-255 (1977).
23. Faudon, J. F., Senocq, F., Bergeret, G., Moroweck, B., Clugnet, G., Nicot, C., Renouprez, A., "Properties of Supported Pd-Ni Catalysts Prepared by Coexchange and by Organometallic Chemistry. 1. Preparation and Characterization by X-Ray-Diffraction, Analytical Microscopy and EXAFS", J. Catal., Vol 144, 460-471 (1993).
24. 3 catalysts (Me = Mo, V and Pb)", J. Molec Catal. A: Chemical, Vol 233, 133-139 (2005).
25. Fernández, J. L, White, M., Sun, Y., Tang, W., Henkelman, G., Bard, A. J., "Characterization and Theory of Electrocatalysts Based on Scanning Electrochemical Microscopy Screening Methods", Langmuir, Vol 22, 10426-10431 (2006)
26. Fillion, B., I. Morsi, B. I., "Kinetics, Gas-Liquid Mass Transfer, and Modeling of the Soybean Oil Hydrogenation Process", Ind. Eng. Chem. Res., Vol 41, 697-709 (2002).
27. Froment, G. B., Bischoff, K.B., "Chemical Reactor Analysis and Design", John Willey and Sons, New York, Vol 2 (1990).
28. Furlong, B.K., Hightower, J.W., Chan, T.Y-L., Sarkany, A., Guczi, L., "1-3-Butadiene Selective Hydrogenation over Pd/Alumina and Cu-Pd/Alumina Catalysts ", Appl. Catal. A, Vol 117, 41- 51 (1994).
29. Galarneau, A., Cambon, H., Di Renzo, F., Fajula, F., "True microporosity and surface area of mesoporous SBA-15 silicas as a function of synthesis temperature" Langmuir, Vol 17, 8328-8335 (2001).
30. Jonker, G. H., "Hydrogenation of Edible Oils and Fats", PhD Thesis, Groningen University, The Netherlands (1999).
31. Marrone, G.M., Kirwan, D.J., "Mass-Transfer to Suspended Particles in Gas-Liquid Agitated Systems", A. I. Ch. E. J. Vol 32, 523-525 (1986).
32. Gopalani, M., Shahare, M., S. Ramteke, D.S., Wate, S. R., "Heavy Metal Content of Potato Chips and Biscuits from Nagpur City, India", Bull. Environ Contamination Toxicol, Vol 79, 384-387 (2007).
33. Guczi, L., Z., Schay, Stefler, G. Y., Liotta, L.F., Deganello, G., Venezia, A.M., "Pumice-Supported Cu-Pd catalysts: Influence of Copper on the Activity and Selectivity of Palladium in the Hydrogenation of Phenylacetylene and But-1-ene", J. Catal., Vol 182, 456-462 (1999).
34. 2 Reaction over Fe-Ru Bimetallic Catalysts", Appl. Catal., Vol 22, 289-309 (1986).
35. Inga, J. R., Morsi, B. I., "A Novel Approach for the Assessment of the Rate-Limiting Step in Fischer-Tropsch Slurry Process", Energy Fuels, Vol 10, 566-572 (1996).
36. Kielhorna, J., Melberb, C., Kellerb, D., Mangelsdorfa, I., "Palladium - A Review of Exposure and Effects to human health", Int. J. Hyg. Environ. Health, Vol 205, 417-432 (2002).
37. Lambelet, P., "Comparison of NMR and DSC Methods for Determining Solid Content of Fats Application to Milk-Fat and its Fractions", Lebensmittel-Wissenschaft & Technologie, Vol 16, 200-202 (1983).
38. Lindlar, H., " Ein neuer Katalysator für selektive Hydrierungen ", Helv. Chim. Acta, Vol 35, 446-450 (1952).
39. Lynch, J., "Spectroscopic des photoelectrons X, in Analyse physico-chimique des catalyseurs industriels. Manuel pratique de caractérisation", Chapitre 5, J. Lynch Ed., Editions Technip, Paris, p. 89-109 (2001).
40. Masai, M., Honda, K., Kubota, A., Onhaka, S., Nishikawa, Y., Nakahara, K., Kishi, K., Ikeda, S., "Dehydrogenation and Hydrogenation Activity of Palladium -Tin-Silica and Nickel-Tin-Silica ", J. Catal. Vol 50, 419-428 (1977).
41. Massard, R, Uzio, D, Thomazeau, C, Pichon, C, Rousset, J.L, Bertolini, J.C, Strained, " Pd Overlayers on Ni Nanoparticles Supported on Alumina and Catalytic Activity for Buta-1,3-Diene Selective Hydrogenation ", J. Catal., Vol, 133-143 (2007).
42. Criinert, W, Stakheev, A. Y, Feldhaus, R., Anders, K., Shpiro, E.S, Minachev, K. M., "Analysis of Mo(3d) XPS Spectra of Supported Mo Catalysts: An Alternative Approach", J. Phys. Chem. Vol 95, 1323-1328 (1991).
43. Moulder, J. F., Stickle, W. F., Sobol P.E., Bomben, K. D., "Handbook of X-ray Photoelectron Spectroscopy", Perkin-Elmer Corp., Eden Prairie, MN, (1992).
44. Noronha, F.B., Schmal, M., Fréty, R., Bergeret, G., Moraweck, B., "Evidence of Alloy Formation During the Activation of Graphite-Supported Palladium-Cobalt Catalysts", J. Catal., Vol 186, 20-30 (1999).
45. Noronha, F.B., Baldanza, M.A.S., Schmal, M., "Co and No Adsorption on Alumina-Pd-Mo Catalysts: Effect of the Precursor Salts", J. Catal., Vol 188, 2770-280 (1999)
46. Oomen, C. M., Ocke, M. C., "Association Between trans Fatty Acid Intake and 10-Year Risk of Coronary Heart Disease in the Zutphen Eldery Study: a Prospective Population-Based Study", Lancet-British-Edition, Vol 357, 746 (2001).
47. Palczewska, W., Jablonski, A., Kaszkur, Z., "Study on Lead Additives in Modified Palladium Catalysts", J. Mol. Catal., Vol 25, 307-316 (1984).
48. Pawelec, B, Daza, L, Fierro, J. L. G, "Regeneration of Ni-USY Catalysts used in Benzene Hydrogenation", Appl. Catal. A- General, Vol 145, 307-322 (1996).
49. Pihl, M., Schöön N. H., "Rate Factors in Liquid Phase Hydrogenation. 1. Kinetics of Hydrogenation of Cottonseed Oil in Presence of a Solid Catalyst", Acta Polytech. Scand. Chem. Ind. Met. Ser, Vol 100, 3-8 (1971)
50. Plourde, M., Arul, J., Belkacemi, K., "Hydrogenation of Sunflower Oil with Novel Catalysts Supported on Structured Silica", Ind. Eng. Chem. Res., Vol. 43, 2382-2390 (2004).
51. th AOCS Meeting and Expo, KansasCity, Missouri, USA, May 4-7 (2003).
52. 2 Supported Pd-Ru Bimetallic Catalyst for the Partial Hydrogenation of Palm oil", React. Kinet. Catal. Lett, Vol 85, 223-229 (2005).
53. Sales, E. A., Mendes, M. J., Bozon-Verduraz, F., "Palladium, palladium-tin, and palladium-silver catalysts in the selective hydrogenation of hexadienes: TPR, Mossbauer, and infrared studies of adsorbed CO", J. Catal. Vol 195, 88-95 (2000).
54. Sarkany, A; Zsoldos, Z. Furlong, B. Hightower, J.W. Guczi, L. "Hydrogenation of 1-Butene and 1,3-Butadiene Mixtures over Pd/ZnO Catalysts", J. Catal., Vol 141, 566-582 (1993).
55. Grosvenora, A. P., Mark I., Biesingera, C., Smart R.S., McIntyre, N. S., "New Interpretations of XPS Spectra of Nickel Metal and Oxides", Surf. Sci., Vol 600, 1771-1779 (2006).
56. Cheong, W.-J., Luan, B. L., McIntyre, N. S., Shoesmith, D. W., "XPS Characterization of the Corrosion Film Formed on the Electrodes Nickel Deposit Prepared using Different Stabilizers in NaCl Solution", Surf. Interf. Anal., Vol 39, 405-414 (2007).
57. Satterfield, C.N., "Mass Transfer in Heterogeneous Catalysis", MIT Press, Cambridge, MA, (1970).
58. Thompson, R. H., "Direct Measurement of Total trans- and cis- Octadecenoic Fatty Acids Based on a Gas-Liquid Chromatographic Class Separation of trans-18:1 and cw-18:1 Fatty Acid Methyl Esters", J. Chrom. Sci., Vol 35, 536-544 (1997).
59. Unnikrishnan, R. P, Endalkachew, S-D., "Strontium as an Efficient Promoter for Supported Palladium Hydrogenation Catalysts", Appl. Catal. A: General, Vol 281, 31-38 (2005).
60. Vassileva, M.N, Andreev, A.A., Shopov, D. M., "Effect of Molybdena on the Activity and Dispersity of Supported Palladium Catalysts for liquid-Phase Hydrogenation", React. Kinet. Catal. Lett., Vol 22, 165-169 (1983).
61. Wright, A. J., Mihele, A. L., Diosady, L.L., "Cis-Selectivity of Mixed Catalyst Systems in Canola Oil Hydrogenation", Food Res. Int. Vol 36, 797-804 (2003).
62. Zhao, D.Y, Feng, J. L., Huo, Q. S, Melosh, N., Fredrickson, G.H, Chmelka, B.F, Stucky, G.D, "Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores", Science, Vol 279, 548-552 (1998).
63. Zueva, L. I., Skol'skii, D. V., "Low Temperature Hydrogenation of Vegetable Oils on Catalysts of the Platinum Group Deposited on Carbon", Tr. Inst. Khim. Nauk. Acad. Nauk Kaz. S.S.R, Vol 13, 146-158 (1965).