Effect of the polycarbosilane structure on its final ceramic yield

Journal of the European Ceramic Society

Volumn 28, Issue 4, 2008, Pages 887-891

  Li, Houbu ^a   Zhang, Litong ^a   Cheng, Laifei ^a   Wang, Yiguang ^a   Yu, Zhaoju ^b   Huang, Muhe ^b   Tu, Huibin ^b   Xia, Haiping ^b  

^a NORTHWESTERN POLYTECHNICAL UNIVERSITY   (China)

^b Key Laboratory for Chemical Biology of Fujian Province   (China)

Author keywords

Ceramic yield; Cross linking; Polycarbosilane structure; Precursors organic; SiC

Indexed keywords

CROSSLINKING; HEAT TREATMENT; MOLECULAR WEIGHT; POLYMERS; STRUCTURE (COMPOSITION);

CERAMIC YIELD; POLYCARBOSILANE;

CERAMIC MATERIALS;

CERAMIC MATERIALS; CROSSLINKING; HEAT TREATMENT; MOLECULAR WEIGHT; POLYMERS; STRUCTURE (COMPOSITION);

EID: 37549007972     PISSN: 09552219     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jeurceramsoc.2007.07.020     Document Type: Article

References (28)

1. Yajima S., Hasegawa Y., Okamura K., and Matsuzawa T. Development of high tensile strength silicon carbide fiber using an organosilicon polymer precursor. Nature 273 (1978) 525-527
2. Riedel R., Passing G., SchoÈnfelder H., and Brook R.J. Synthesis of dense silicon-based ceramics at low temperatures. Nature 355 (1992) 714-717
3. Riedel R., Kienzle A., Dressler W., Ruwisch L., Bill J., and Aldinger F. A silicoboron carbonitride ceramic stable to 2000 °C. Nature 382 (1996) 796-798
4. An L., Riedel R., Konetachny C., Kleebe H.J., and Raj R. Newtonian viscosity of amorphous silicon carbo-nitride at 1280 °C. J. Am. Ceram. Soc. 81 (1998) 1349-1352
5. Riedel R., Ruwisch L.M., An L., and Raj R. Amorphous silicoboron carbonitride ceramic with very high viscosity at temperatures above 1500 °C. J. Am. Ceram. Soc. 81 (1998) 3341-3344
6. Wang Y., Fan Y., Zhang L., Burton S., Gan Z., and An L. Oxidation of polymer-derived SiAlCN ceramics. J. Am. Ceram. Soc. 88 (2005) 3075-3080
7. Wang Y., Fan Y., Zhang L., Zhang W., and An L. Polymer-derived SiAlCN ceramics resist oxidation at 1400 °C. Scripta Mater. 55 (2006) 295-297
8. Wang Y., Fei W., and An L. Oxidation/corrosion of polymer-derived SiAlCN ceramics in water vapor. J. Am. Ceram. Soc. 89 (2006) 1079-1082
9. Wang Y., Fei W., Fan Y., Zhang L., Zhang W., and An L. Silicoaluminum carbonitride ceramic resist to oxidation/corrosion in water vapor. J. Mater. Res. 21 (2006) 1625-1628
10. Eigen P., Keller-Rudek H., Kurtz W., Merlet P., Schaefer H., and Schroeder F. Gmelin handbook of inorganic chemistry. 8th ed. (1989), Silicon Suppl., Berlin
11. Pawlenko S. In: Bayer O., and MuÈller E. (Eds). Methoden der organischen Chemie (Houben-Weyl), Vol 13, part 5. 4th ed. (1980), Georg Thieme, Stuttgart
12. Birot M., Pillot J.P., and Dunogues J. Comprehensive chemistry of polycarbosilanes, polysilazane, and polycarbosilazanes as precursors of ceramics. Chem. Rev. 95 (1995) 1443-1447
13. Kroke E., Li Y., Konetschny C., Lecomte E., Fasel C., and Riedel R. Silazane derived ceramics and related materials. Mater. Sci. Eng. R 26 (2000) 97-199
14. Wynne K.J., and Rice R.W. Ceramics via polymer pyrolysis. Annu. Rev. Mater. Sci. 14 (1984) 297-334
15. Seyferth D. In: Zeldin M., Wynne K.J., and Allcock H.R. (Eds). Inorganic and organometallic polymers, ACS Symposium Series 360 (1988), American Chemical Society, Washington, DC
16. 4/SiC ceramic materials by pyrolysis of a novel polyorganosilazane. J. Am. Ceram. Soc. 67 (1984) C132-C133
17. Lücke J., Hacker J., Suttor D., and Ziegler G. Synthesis and characterization of silazane-based polymers as precursors for ceramic matrix composites. Appl. Organomet. Chem. 11 (1997) 181-194
18. Lavedrine A., Bahloul D., Goursat P., Choong Kwet Yive N., Corriu R., Leclerq D., et al. Pyrolysis of polyvinylsilazane precursors to silicon carbonitride. J. Eur. Ceram. Soc. 8 (1991) 221-227
19. Bahloul D., Pereira M., Goursat P., Choong Kwet Yive N.S., and Corriu R.J.P. Preparation of silicon carbonitrides from an organosilicon polymer. I. Thermal decomposition of the cross-linked polysilazane. J. Am. Ceram. Soc. 76 (1993) 1156-1162
20. Huang T.H., Yu Z.J., He X.M., Huang M.H., Chen L.F., Xia H.P., et al. One-pot synthesis and characterization of a new, branched polycarbosilane bearing allyl groups. Chin. Chem. Lett. 18 (2007) 754-757
21. Bouillon E., Langlais F., Pailler R., Naslain R., Cruege F., Huong P.V., et al. Conversion mechanisms of a polycarbosilane precursor into an SiC-based ceramic material. J. Mater. Sci. 26 (1991) 1333-1345
22. Hasegawa Y., and Okamura K. Synthesis of continuous silicon carbide fiber. IV. The structure of polycarbosilane as the precursor. J. Mater. Sci. 21 (1986) 321-328
23. LY H.Q., Taylor R., Day R.J., and Heatley F. Conversion of polycarbosilane (PCS) to SiC-based ceramic. Part 1. Characterization of PCS and curing products. J. Mater. Sci. 36 (2001) 4037-4043
24. Rushkin I.L., Shen Q., Lehman S.E., and Interrante L.V. Modification of a hyperbranched hydridopolycarboxysilanes as a route to new polycarbosilanes. Macromolecules 30 (1997) 3141-3146
25. Peter E.F. Synthesis and properties of a new, branched polyhydridocarbosilane as a precursor for silicon carbide. J. Inorg. Organomet. Polym. 3 3 (1993) 251-258
26. Whitmarsh C.K., and Interrante L.V. Synthesis and Structure of a highly branched polycarbosilane derived from (chloromethy1)trichiorosilane. Organometallics 10 (1991) 1336-1344
27. Matthews S., Edirisinghe M.J., and Folkes M.J. Effect of pre-pyrolysis heat treatment on the preparation of silicon carbide from a polycarbosilane precursor. Ceram. Int. 25 (1999) 49-60
28. Mocaer D., Pailler R., Naslain R., Richard C., Pillot J.P., Dunogues J., et al. Si-C-N ceramics with a high microstructural stability elaborated from the pyrolysis of new polycarbosilazane precursors. Part I. The organic/inorganic transition. J. Mater. Sci. 28 (2001) 2615-2631