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Reference 1b, p 130.
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28
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85033171110
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note
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See Supporting Information for the experimental details and/ or actual spectra or NMR profiles.
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29
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85033164287
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note
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n-3 sites and the various possible X groups (H, OH, and R) at each site.
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30
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85033178359
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note
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Our experience indicates that the elemental analyses for this type of polymer are not very reproducible. This problem could arise from the tendency of carbosilanes to form silicon carbide (or oxycarbide) on pyrolysis, rendering the complete combustion of the carbon difficult. For example, all of the analyses given above were done at Galbraith Laboratories, Inc., Knoxville, TN. Several of the same samples were also sent to Guelph Chemical Laboratories Ltd., Guelph, Ontario, Canada. The results are as follows, for allyl-substituted HBPSE: C, 61.72; H, 9.54. for butyl-substituted HBPSE: C, 66.11; H, 13.05. for phenyl-substituted HBPSE: C, 79.12; H, 6.17. Obviously, the analyses from Galbraith Laboratories give the most conservative estimate of the degree of substitution.
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85033163109
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An Introduction to Organosilicon Chemistry
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Huls America Inc.
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See for example: (a) Larson, G. L. An Introduction to Organosilicon Chemistry. In Silicon Compounds, Register and Review; Huls America Inc.: 1991; p 11. (b) Kendric, T. C.; Parbhoo, B.; White, J. W. Siloxane Polymers and Copolymers In The Chemistry of Silicon Compounds; Patai, S., Rappoport, Z., Eds.; J. Wiley & Sons: New York, 1989; p 1342. (c) Liao, C. X.; Weber, W. P. Macromolecules 1993, 26 (4), 563.
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Larson, G.L.1
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Siloxane Polymers and Copolymers
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Patai, S., Rappoport, Z., Eds.; J. Wiley & Sons: New York
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See for example: (a) Larson, G. L. An Introduction to Organosilicon Chemistry. In Silicon Compounds, Register and Review; Huls America Inc.: 1991; p 11. (b) Kendric, T. C.; Parbhoo, B.; White, J. W. Siloxane Polymers and Copolymers In The Chemistry of Silicon Compounds; Patai, S., Rappoport, Z., Eds.; J. Wiley & Sons: New York, 1989; p 1342. (c) Liao, C. X.; Weber, W. P. Macromolecules 1993, 26 (4), 563.
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The Chemistry of Silicon Compounds
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Kendric, T.C.1
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0027543677
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See for example: (a) Larson, G. L. An Introduction to Organosilicon Chemistry. In Silicon Compounds, Register and Review; Huls America Inc.: 1991; p 11. (b) Kendric, T. C.; Parbhoo, B.; White, J. W. Siloxane Polymers and Copolymers In The Chemistry of Silicon Compounds; Patai, S., Rappoport, Z., Eds.; J. Wiley & Sons: New York, 1989; p 1342. (c) Liao, C. X.; Weber, W. P. Macromolecules 1993, 26 (4), 563.
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Liao, C.X.1
Weber, W.P.2
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34
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85033163987
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Private communication
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A one-step synthesis of this oligomer with about 90% allyl substitution has been developed in our laboratory and will be published elsewhere (Shen, Q.; Interrante, L. V. Private communication).
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Shen, Q.1
Interrante, L.V.2
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Fish, D.1
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See for example: (a) Fish, D.; Khan, I. M.; Wu, E.; Smid, J. Br. Polym. J. 1988, 20, 281. (b) Splindler, R.; Shriver, D. F. Macromolecules 1988, 21, 648.
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