The decarboxylative blaise reaction

Journal of Organic Chemistry

Volumn 72, Issue 26, 2007, Pages 10261-10263

  Jae, Hoon Lee ^a   Bo, Seung Choi ^a   Jay, Hyok Chang ^a   Hee, Bong Lee ^a   Yoon, Joo Yong ^a   Lee, Jaeick ^a   Shin, Hyunik ^a  

^a LG Chemical Ltd   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ARYL NITRILES; HUNIG'S BASE; LACHRYMATORY REAGENTS; POTASSIUM ETHYL MALONATE;

ALKALINITY; NITRILE RESINS; REACTION KINETICS; ZINC COMPOUNDS;

ORGANIC COMPOUNDS;

3 AMINO 3 (2,4,5 TRIFLUOROPHENYL)ACRYLIC ACID ETHYL ESTER; 3 AMINO 3 (3 METHOXYPHENYL)ACRYLIC ACID ETHYL ESTER; ACRYLIC ACID DERIVATIVE; BASE; BENZONITRILE; BETA AMINO ACRYLIC ACID; MALONIC ACID; NITRILE; POTASSIUM; REAGENT; UNCLASSIFIED DRUG; ZINC CHLORIDE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; DECARBOXYLATION;

ACRYLATES; CATALYSIS; CHLORIDES; DECARBOXYLATION; MALONATES; MOLECULAR STRUCTURE; NITRILES; POTASSIUM; SOLVENTS; ZINC COMPOUNDS;

EID: 37548999826     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo701743m     Document Type: Article

References (17)

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10. For an excellent recent review on the transition metal-catalyzed decarboxylative addition of enolates, see: Tunge, J. A.; Burger, E. C. Eur. J. Org. Chem. 2005, 1715.
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13. Recently a decarboxylative aldol reaction catalyzed by Cu(II) species has been disclosed by the Shair group. See: (a) Lalic, G.; Aloise, A. D.; Shair, M. D. J. Am. Chem. Soc. 2003, 125, 2852.
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16. For a heterobimetallic version, see: (d) Lou, S.; Westbrook, J. A.; Schaus, S. E. J. Am. Chem. Soc. 2004, 126, 11440.
17. Please refer to ref 4b.