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Volumn 46, Issue 25, 2007, Pages 10467-10469

Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Author keywords

[No Author keywords available]

Indexed keywords

FERROUS ION; OXYGEN DERIVATIVE; THIOL DERIVATIVE; VANADIUM;

EID: 37349114073     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7017117     Document Type: Article
Times cited : (7)

References (30)
  • 14
    • 37349077801 scopus 로고    scopus 로고
    • Crystallographic data for 1: C66H110N 2O4S4Si2V2, M r, 1281.91; a green crystal (0.45 x 0.50 x 0.60 mm) sealed in a capillary with epoxy, T, 200(2) K, λ(Mo Kα, 0.710 73 Å, monoclinic, space group P21/n, a, 17.2370(2) Å, b, 24.1280(3) Å c, 17.7430(2) Å, V, 7153.40(15) ̊3, Z, 4, ρcalcd, 1.190 g cm-3, 2θmax, 50.16°, μ, 0.455 mm -1, empirical absorption correction using SADABS, F(000, 2760, 43 307 reflections, 12 368 unique reflections (Rint, 0.0565, 721 parameters, 0 restraint, GOF, 1.072, R1, 0.0499 [I > 2σI, wR2, 0.1175, min/max residual electron density -0.482/0.686 e Å-3, refined on |F2
    • 2|.
  • 17
    • 37349020893 scopus 로고    scopus 로고
    • Crystallographic data for 2·H2O: C 53H67NO6S4P2V 2, Mr, 1106.28; a green crystal (0.30 x 0.40 x 0.45 mm) sealed in a capillary with epoxy, T, 200(2) K, λ(Mo Kα, 0.710 73 Å, monoclinic, space group P21/n, a, 9.7871(4) Å, b, 20.9209(10) Å, c, 26.7300(14) Å, V, 5436.2(4) Å3, Z, 4, ρcalcd, 1.355 g cm-3, 2θmax, 52.08°, μ, 0.605 mm-1, empirical absorption correction using SADABS, F(000, 2332, 23 194 reflections, 10 116 unique reflections (Rint, 0.0651, 613 parameters, 0 restraint, GOF, 1.170, R1, 0.0772 [I > 2σI, wR2, 0.1881, min/max residual electron density -0.957/0.815 e Å-3, refined on F 2
    • 2.
  • 18
    • 85008887191 scopus 로고    scopus 로고
    • The O atom is not protonated if the BVS is ∼2; it is monoprotonated if the BVS is ∼1. Brown, I. D. The bond valence method: an empirical approach to chemical structure and bonding. In Structures and Bonding in Crystals; O'Keefe, M., Navrotdsky, A., Eds.; Academic Press: New York, 1981; pp 1-30.
    • The O atom is not protonated if the BVS is ∼2; it is monoprotonated if the BVS is ∼1. Brown, I. D. The bond valence method: an empirical approach to chemical structure and bonding. In Structures and Bonding in Crystals; O'Keefe, M., Navrotdsky, A., Eds.; Academic Press: New York, 1981; pp 1-30.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.