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Volumn 118, Issue 32, 1996, Pages 7568-7573

Evidence for the Michaelis-Menton type mechanism in the electrocatalytic oxidation of mercaptopropionic acid by an amavadine model

Author keywords

[No Author keywords available]

Indexed keywords

3 MERCAPTOPROPIONIC ACID; METAL COMPLEX; VANADIUM DERIVATIVE;

EID: 0029782963     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9607042     Document Type: Article
Times cited : (51)

References (27)
  • 3
    • 9444245055 scopus 로고    scopus 로고
    • Fraústo da Silva, J. J. R. et. al., work in progress
    • Fraústo da Silva, J. J. R. et. al., work in progress.
  • 7
    • 68349101414 scopus 로고
    • Bayer, E.; Kneifel, H. Z. Naturforsch. 1972, 27B, 207. Kneifel, H.; Bayer, E. Angew. Chem., Int. Ed. Engl. 1973, 12, 508.
    • (1972) Z. Naturforsch. , vol.27 B , pp. 207
    • Bayer, E.1    Kneifel, H.2
  • 9
    • 84861957239 scopus 로고
    • Fraústo da Silva, J. J. R. Chem. Speciation Bioavailability 1989, 1, 139. A similar function for vanadium in tunicates has also been proposed, although the metal is in a lower oxidation state, see: Smith, K. J. Experientia 1989, 45, 452, and references therein.
    • (1989) Chem. Speciation Bioavailability , vol.1 , pp. 139
    • Fraústo Da Silva, J.J.R.1
  • 10
    • 0024970450 scopus 로고
    • and references therein
    • Fraústo da Silva, J. J. R. Chem. Speciation Bioavailability 1989, 1, 139. A similar function for vanadium in tunicates has also been proposed, although the metal is in a lower oxidation state, see: Smith, K. J. Experientia 1989, 45, 452, and references therein.
    • (1989) Experientia , vol.45 , pp. 452
    • Smith, K.J.1
  • 11
    • 0002362882 scopus 로고
    • Lund, H., Baizer, M. M., Eds.; Chapter 17. Oxidation of sulfur containing compounds: Marcel Dekker: New York
    • Svensmark, B.; Hammerich, O. In Organic electrochemistry: An introduction and a guide, 3rd ed.; Lund, H., Baizer, M. M., Eds.; Chapter 17. Oxidation of sulfur containing compounds: Marcel Dekker: New York, 1991; p 659.
    • (1991) Organic Electrochemistry: An Introduction and a Guide, 3rd Ed. , pp. 659
    • Svensmark, B.1    Hammerich, O.2
  • 15
    • 9444248197 scopus 로고    scopus 로고
    • note
    • a value of the functional thiol group of our substrates (e.g., 10.8 for mercaptoacetic acid, see ref 13b), these are practically all in the acid (-SH) form; (iii) the form of the carboxylic functional groups of our substrates should not play a relevant role in view of the recognized (see also ref 10b) activity for thiols with either a carboxylic or an ester group.
  • 23
    • 9444239822 scopus 로고    scopus 로고
    • note
    • elio. For this reason Figure 4 is presented as two different panels: (a) presents the raw results, and (b) only these which bear kinetic sense based on the experimental error.
  • 25
    • 9444220826 scopus 로고    scopus 로고
    • note
    • 20


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