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Volumn 323, Issue 1, 2008, Pages 105-203

Nonlinear elasticity, fluctuations and heterogeneity of nematic elastomers

Author keywords

61.41.+e; 64.60.Ak; 64.60.Fr; Anomalous elasticity; Critical phase; Fluctuations; Goldstone modes; Liquid crystals; Micropolar elasticity; Nematic elastomer; Nonlinear elasticity; Poisson ratio; Quenched disorders; Renormalization group; Scaling; Symmetry breaking; Zero temperature fixed point

Indexed keywords


EID: 37349090460     PISSN: 00034916     EISSN: 1096035X     Source Type: Journal    
DOI: 10.1016/j.aop.2007.10.009     Document Type: Article
Times cited : (25)

References (94)
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    • note
    • ij appearing in elasticity of the resulting crystal.
  • 5
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    • note
    • It is fair to say that no complete description of structural glasses exists at the moment. One school of thought advocates glasses to be indistinguishable from ordinary fluids in their thermodynamic static properties, but with an extremely large viscosity that makes them behave elastically on experimentally accessible time scales.
  • 11
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    • note
    • It is worth to note that recently a rather sophisticated analytical approach for these vulcanized materials was developed [75,76], which seems to be able to capture the network heterogeneity. Further studies within the framework of this vulcanization theory may yield information on details of rubber heterogeneity, that for the purposes of the present work we take as a working assumption.
  • 12
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    • X. Xing, P.M. Goldbart, L. Radzihovsky, Phys. Rev. Lett. 98 (2007) 075502 (pages 4). Available from: .
  • 16
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    • note
    • One possibility is the slowness of equilibration rates (outside of experimentally accessible time scales) toward a nematically-ordered thermodynamic ground state. Another, is the intrinsic thermodynamic instability of the nematic order in the presence of polymer network heterogeneities. Distinguishing between these two qualitatively distinct possibilities is in fact one of the fundamental goals of this theoretical research, paralleling similar efforts in random magnets [92].
  • 24
    • 37349031151 scopus 로고    scopus 로고
    • note
    • For a brief account of history, see Ref. [51].
  • 37
    • 37349041096 scopus 로고    scopus 로고
    • note
    • The reader may notice the similarity between this soft mode of nematic elastomers and rotation of layers in a smectic liquid crystal. However, there is a qualitative difference. In a smectic liquid crystal, the nematic director is always locked to the layer normal, while, in contrast, in a nematic elastomer, the nematic director is tilted away from the principle axis of the elastic soft deformation.
  • 38
    • 37349000632 scopus 로고    scopus 로고
    • note
    • It is worth noting that a three-dimensional system with power-law correlations phenomenology extending across a whole phase has been a holy-grail in the field of quantum strongly-correlated systems, where it is hoped to explain anomalous experimental observations in a variety of materials that do not neatly fall into conventional (e.g., Landau's Fermi liquid) solid state paradigm [93].
  • 39
    • 37349004164 scopus 로고    scopus 로고
    • note
    • Such a first-order transition is not seen in real experiment, believed to be destroyed by gel's heterogeneity [19].
  • 40
    • 37349088682 scopus 로고    scopus 로고
    • note
    • We adopt this terminology from Ogden [53].
  • 41
    • 37349128591 scopus 로고    scopus 로고
    • note
    • This type of abuse of notations is common for physicists. Rigorously speaking, we should use different notation for the functions when we change the variable, i.e., over(over(r, →), ̃) (over(x, →)) = over(r, →) (over(X, →)) etc.
  • 43
    • 37349117710 scopus 로고    scopus 로고
    • note
    • For a detailed discussion, see Ref. [53].
  • 44
    • 37349124923 scopus 로고    scopus 로고
    • note
    • Which is usually called the left Cauchy-Green strain tensor in nonlinear elasticity theory.
  • 45
    • 37349040406 scopus 로고    scopus 로고
    • note
    • 0 of the nematic reference state.
  • 46
    • 37349071079 scopus 로고    scopus 로고
    • note
    • Strictly speaking we should distinguish the Lagrangian volume measured in referential coordinate and the Eulerian volume measure in current coordinate. However, since rubbery materials are nearly incompressible, the difference is usually negligible. We should also be careful with the terms elastic free energy and elastic energy. It is understood that the elastic energies we discuss in this section are really Landau elastic free energy which already included thermal fluctuations below certain length-scale, e.g., that of a mesh size of the polymer network. Fluctuations on a longer length-scale will be studied in later sections.
  • 47
    • 37349009347 scopus 로고    scopus 로고
    • note
    • This elastic energy is equivalent to the one derived in Ref. [29], (Eq. (4.22)), in spite of different notations used there.
  • 48
    • 37349092373 scopus 로고    scopus 로고
    • note
    • e to be the elastic energy per unit volume measured in the nematic referential coordinate over(x, →).
  • 49
    • 37349052430 scopus 로고    scopus 로고
    • note
    • In principle, there may be higher order couplings between director distortion ∇ over(n, ̂) and the deformation gradient λ. We shall not consider them since they are less relevant than the terms we study here.
  • 51
    • 37349050006 scopus 로고    scopus 로고
    • W. Nowacki, Theory of Asymmetric Elasticity (H. Zorski, Trans.), Pergamon Press, 1986.
  • 52
    • 37349056134 scopus 로고    scopus 로고
    • note
    • The discussion from here to the paragraph before Eq. (3.27) also applies to fluid and is not original. The reader can find similar presentations in various textbooks and monographs on micropolar elasticity, such as Ref. [51].
  • 54
    • 37349120780 scopus 로고    scopus 로고
    • note
    • This observation is of course also true for a nematic liquid crystal, and actually is the starting point of nematic hydrodynamics [58].
  • 55
    • 37349010834 scopus 로고    scopus 로고
    • note
    • There is of course a separate contribution to the torque coming from the force transmitted through the surface, which acts on the translational degrees of freedom.
  • 56
    • 37349068225 scopus 로고    scopus 로고
    • note
    • Even a fluid with orientational order, e.g., a nematic liquid crystal, can transmit a torque by this mechanism, as discussed in Ref. [58]
  • 57
    • 37349033262 scopus 로고    scopus 로고
    • note
    • Traction is the standard terminology in elasticity theory for boundary force applied/controlled externally. In physics community, it is often referred to as the external stress. In elasticity theory, the term stress refers exclusively to force per unit area transmitted inside elastic bodies.
  • 59
    • 37349088190 scopus 로고    scopus 로고
    • note
    • In contrast, a phonon field linear in over(x, →) (is unbound and therefore does not have well-defined Fourier transform) corresponds to a macroscopic deformation, which is incompatible with the prescribed constant strain ensemble. Also, we note that the over(q, →) = 0 component of over(u, →) clearly corresponds to a uniform translation of the solid and thus does not contribute to the elastic free energy.
  • 60
    • 37349118725 scopus 로고    scopus 로고
    • note
    • 0.
  • 61
    • 37349089419 scopus 로고    scopus 로고
    • note
    • They are the analogues of the Helmholtz free energy and Gibbs free energy, respectively, in the case of magnetism or gas thermodynamics.
  • 62
    • 37349054747 scopus 로고    scopus 로고
    • note
    • In field theory, such terms are referred to as the "counter terms".
  • 63
    • 37349037924 scopus 로고    scopus 로고
    • note
    • This is quite analogous to many other ordered states, such as for example a ferromagnet, where to include fluctuations, one has a choice of either expanding about a minimum of the Hamiltonian or about a true minimum of the free energy.
  • 64
    • 37349080977 scopus 로고    scopus 로고
    • note
    • This can be easily seen from Eqs. (2.43) and (2.39). For a fixed geometric configuration over(r, →) (over(x, →)), the nematic director fluctuation δ over(n, ̂) is "massively" tied to the strain deformation through the last term in Eq. (2.43), as long as r ≠ 1, i.e., the nematic order does not vanish. This guarantees that the fluctuations of the nematic director are always finite.
  • 65
    • 37349132001 scopus 로고    scopus 로고
    • note
    • In the case of an arbitrary d dimension, it is clear that only the first d of these invariants are independent.
  • 67
    • 37349011557 scopus 로고    scopus 로고
    • note
    • ⊥ field, but does not affect the RG analysis. We shall consider this term again in the renormalized theory.
  • 68
    • 37349017652 scopus 로고    scopus 로고
    • note
    • The small region in over(q, →) space where this is not true is not important for calculation of real space fluctuations.
  • 73
    • 37349035369 scopus 로고    scopus 로고
    • note
    • It is however not clear whether exactly the same configuration is restored. Neither is it known whether the experimentally observed isotropic-polydomain transition is a genuine phase transition, or just a continuous cross-over.
  • 79
    • 37349109738 scopus 로고    scopus 로고
    • X. Xing, L. Radzihovsky, unpublished.
  • 80
    • 37349111837 scopus 로고    scopus 로고
    • note
    • We emphasize that nematic elastomers are amorphous solids with no microscopic lattice structure, or long-range translational order of any kind. This is an essential feature that distinguishes them (and other amorphous solids) from crystalline solids and liquid crystals with quenched structural disorder. In the latter systems, there is a natural periodic reference state with perfect long range translational order that is deformed by local heterogeneity and is a natural reference state about which to expand any other (including a true ground) state. By contrast, in amorphous solids like nematic elastomers, no such natural reference state exists other than the true ground state. Since our isotropic reference state is not the ground state, it is completely arbitrary, a conceptually convenient construction. Consequently, the "phonon field" over(u, →) defined relative to this fictitious reference state, has a priori no absolute meaning, i.e., is "fictitious". However, for a given realization of disorders, there is a well-defined relation between the physical phonon field δ over(r, →), defined relative to the true ground state, and the fictitious phonon field over(u, →), which is defined relative to the IRS. As we shall show later in this paper, the quenched correlation function of over(u, →) encodes information about the correlation of the nonaffine displacement field when the system is macroscopic strained.
  • 81
    • 37349009346 scopus 로고    scopus 로고
    • note
    • A more natural definition of the physical phonon field is the displacement from the average position of mass points. See Section 4.2 for a discussion of this issue.
  • 82
    • 37349020327 scopus 로고    scopus 로고
    • note
    • For a review of replica method applied to disordered systems, see references [94].
  • 86
    • 37349010712 scopus 로고    scopus 로고
    • note
    • The subscript g stands for "graphical".
  • 87
    • 37349111095 scopus 로고    scopus 로고
    • note
    • < appropriately.
  • 88
    • 37349100560 scopus 로고    scopus 로고
    • note
    • r stands for "rescaling".
  • 93
    • 29644437233 scopus 로고    scopus 로고
    • M. Hermele, T. Senthil, M.P.A. Fisher, Physical Review B (Condensed Matter and Materials Physics) 72 (2005) 104404 (pages 16). Available from: .


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.