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Volumn , Issue 19, 2007, Pages 3019-3021

A new heterogeneous one-pot process for both nitroaldol (Henry) and Michael reactions from primary haloalkanes via nitroalkanes

Author keywords

Haloalkanes; Henry reaction; Heterogeneous process; Michael addition; Nitroaldol reaction; Nitroalkanes; One pot process

Indexed keywords

ALKANE DERIVATIVE; ALKANOL; BETA NITROALANOL DERIVATIVE; GAMMA NITRO KETONE DERIVATIVE; HALOALKANE DERIVATIVE; KETONE DERIVATIVE; NITROALKANE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 37349004548     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-990973     Document Type: Article
Times cited : (7)

References (29)
  • 6
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    • Trost, B. M, Ed, Pergamon: Oxford
    • (a) Rosini, G. In Comprehensive Organic Synthesis, Vol. 2; Trost, B. M., Ed.; Pergamon: Oxford, 1991, 321.
    • (1991) Comprehensive Organic Synthesis , vol.2 , pp. 321
    • Rosini, G.1
  • 9
    • 77957040775 scopus 로고    scopus 로고
    • In Studies in Natural Products Chemistry
    • See for example: a, Elsevier: Amsterdam
    • See for example: (a) Ballini, R. In Studies in Natural Products Chemistry, Vol. 19; Atta-ur-Rahman, Ed.; Elsevier: Amsterdam, 1997, 117.
    • (1997) Atta-ur-Rahman, Ed , vol.19 , pp. 117
    • Ballini, R.1
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    • 0347707711 scopus 로고
    • (a) Amato, J. Science 1993, 259, 1538.
    • (1993) Science , vol.259 , pp. 1538
    • Amato, J.1
  • 22
    • 37349060556 scopus 로고    scopus 로고
    • 4), filtered and evaporated yielding a crude product that was purified by flash chromatography (cyclohexane-EtOAc as eluent), giving the pure compound 6 or 7.
    • 4), filtered and evaporated yielding a crude product that was purified by flash chromatography (cyclohexane-EtOAc as eluent), giving the pure compound 6 or 7.
  • 23
    • 37349119929 scopus 로고    scopus 로고
    • Selected Analytical Data for Compounds 6b,c and 7a,b: Compound 6b: yellow oil. IR (neat, 1456, 1916, 3354 cm-1. 1H NMR (400 MHz, CDCl3, δ, 0.86-0.92 (m, 3 H, 1.21-1.40 (m, 4 H, 1.60-1.93 (m, 3 H, 1.96-2.17 (m, 1 H, 2.32 (d, J, 8.1 Hz, 0.6 H, 2.45 (d, J, 4.3 Hz, 0.4 H, 2.65-2.80 (m, 1 H, 2.82-2.96 (m, 1 H, 3.82-3.94 (m, 0.6 H, 3.97-4.06 (m, 0.4 H, 4.40-4.49 (m, 1 H, 7.16-7.34 (m, 5 H, 13C NMR (100 MHz, δ, 13.9, 14.0, 22.3, 22.4, 27.9, 28.0, 28.3, 30.4, 31.8, 32.1, 35.0, 35.5, 71.4, 71.7, 92.5, 93.1, 126.5, 128.7, 128.8, 141.0. Anal. Calcd for C14H 21NO3: C, 66.91; H, 8.42; N, 5.57. Found: C, 67.24; H, 8.66; N, 5.38. Compound 6c: yellow oil. IR (neat, 1730, 3404 cm-1. 1H NMR (400 MHz, CDCl3, δ, 0.96-1.04 (m, 3 H, 1.37-1.94 (m, 5 H, 2.03-2.21 (m, 1 H, 2.43 (d, J, 7.7 Hz, 0.5 H, 2.54 d, J, 5.1
    • 5: C, 51.94; H, 7.41; N, 6.06. Found: C, 52.23; H, 7.61; N, 5.88.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.