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Volumn , Issue 19, 2007, Pages 2927-2936

Evolution, development and personal experience in studies of the allyl cyanate-to-isocyanate rearrangement

Author keywords

Allyl cyanate; Isocyanate; Natural product synthesis; Rearrangement

Indexed keywords

ALLYL COMPOUND; CARBON; CYANIC ACID DERIVATIVE; ISOCYANATE; NATURAL PRODUCT; NITROGEN;

EID: 37249070241     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-992370     Document Type: Article
Times cited : (50)

References (51)
  • 2
    • 0002166739 scopus 로고
    • For a comprehensive discussion of the rearrangement of allyl thiocyanates, see:, Patai, S, Ed, Wiley-Interscience: New York, Chap. 12
    • (b) For a comprehensive discussion of the rearrangement of allyl thiocyanates, see: Giles, D. E. In The Chemistry of Cyanates and Their Thio Derivatives, Part 1; Patai, S., Ed.; Wiley-Interscience: New York, 1977, Chap. 12, 381.
    • (1977) The Chemistry of Cyanates and Their Thio Derivatives , Issue.PART 1 , pp. 381
    • Giles, D.E.1
  • 9
    • 0000809496 scopus 로고
    • Trost, B. M, Fleming, I, Eds, Pergamon: Oxford
    • (d) Grashey, R. In Comprehensive Organic Synthesis, Vol. 6; Trost, B. M.; Fleming, I., Eds.; Pergamon: Oxford, 1991, 225.
    • (1991) Comprehensive Organic Synthesis , vol.6 , pp. 225
    • Grashey, R.1
  • 15
  • 22
    • 0004914998 scopus 로고    scopus 로고
    • In a study paralleling our exploration of the synthesis of aminobisabolenes, we probed the synthesis of the sulfur-containing natural product agelasidine A using an allyl xanthate-to-dithiocarbonate rearrangement; see: Ichikawa, Y. Tetrahedron Lett. 1988, 29, 4957
    • In a study paralleling our exploration of the synthesis of aminobisabolenes, we probed the synthesis of the sulfur-containing natural product agelasidine A using an allyl xanthate-to-dithiocarbonate rearrangement; see: Ichikawa, Y. Tetrahedron Lett. 1988, 29, 4957.
  • 28
    • 37249065392 scopus 로고    scopus 로고
    • 3. Usual workup followed by silica gel chromatography (hexane → diethyl ether-hexane, 1:2) gave the recovered starting material (1.23 g) and crude products which were purified by recrystallization (ether and hexane) to furnish aminobisabolenes (a 2:1 mixture of 37 and 38, 195 mg, 4.4% yield based upon the consumed starting materials).
    • 3. Usual workup followed by silica gel chromatography (hexane → diethyl ether-hexane, 1:2) gave the recovered starting material (1.23 g) and crude products which were purified by recrystallization (ether and hexane) to furnish aminobisabolenes (a 2:1 mixture of 37 and 38, 195 mg, 4.4% yield based upon the consumed starting materials).
  • 29
    • 0002263538 scopus 로고    scopus 로고
    • 5 and DCC; see:
    • 5 and DCC; see:


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.