Cocaine analysis in hair: Solid-phase microextraction (SPME) versus supercritical fluid extraction (SFE)

Journal of the Canadian Society of Forensic Science

Volumn 40, Issue 3, 2007, Pages 143-149

  Schiavone, S ^a   Marsili, R ^b   Iuliano, G ^c   Ghizzoni, O ^c   Chiarotti, M ^b  

^a Catholic University of Sacred Heart ^*

^b CATHOLIC UNIVERSITY   (Italy)

^c Chemistry Section   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

BENZOYLECGONINE; COCAINE; KERATIN;

ARTICLE; CONTROLLED STUDY; DRUG HYDROLYSIS; DRUG IDENTIFICATION; HAIR ANALYSIS; HUMAN; HUMAN TISSUE; IN VITRO STUDY; ION MONITORING; LIQUID LIQUID EXTRACTION; MASS FRAGMENTOGRAPHY; QUANTITATIVE ANALYSIS; SOLID PHASE MICROEXTRACTION; SUPERCRITICAL FLUID EXTRACTION;

EID: 37049020913     PISSN: 00085030     EISSN: None     Source Type: Journal    
DOI: 10.1080/00085030.2007.10757156     Document Type: Article

References (20)

1. Kintz P.(editor) Drug Testing in Hair, Boca Raton, FL:CRC Press, Inc., 1996.
2. Cone E.J., Yousefneajd D., Darwin W.D., and Maguire T., Testing human hair for drugs of abuse. II. Identification of unique cocaine metabolites in hair of drug abusers and evaluation of decontamination procedures. J. Anal. Toxicol. 1991; 15(5):250–255.
3. Cone E.J., Darwin W.D., and Wang W., The occurrence of cocaine, heroin and metabolites in hair of drug abusers. Forensic Sci. Int. 1993; 63(1–3):55–68.
4. Nakahara Y., and Kikura R., Hair analysis for drugs of abuse. VII. The incorporation rates of cocaine, benzoylecgonine and ecgonine methyl ester into rat hair and hydrolysis of cocaine in rat hair. Arch. Toxicol. 1994; 68(1):54–59.
5. Strano-Rossi S., Bermejo-Barrera A., and Chiarotti M., Segmental hair analysis for cocaine and heroin abuse determination. Forensic Sci. Int. 1995; 70(1–3):211–216.
6. Miller M.L., Donnelly B., and Martz R.M., The forensic application of testing hair for drugs of abuse. NIDA Res. Monogr. 1997; 167:146–160.
7. Joseph R.E., Jr., Tsai W.J., Tsao Li, Su T.P., and Cone E.J., In vitro characterization of cocaine binding sites in human hair. J. Pharmacol. Exp. Ther. 1997; 282(3):1228–1241.
8. Hold K.M., Wilkins D.G., Rollins D.E., Joseph R.E., Jr., and Cone E.J., Simultaneous quantitation of cocaine, opiates, and their metabolites in human hair by positive ion chemical ionization gas chromatography-mass spectrometry. J. Chromatogr. Sci. 1998; 36(3):125–130.
9. Sachs H., and Kintz P., Testing for drugs in hair. Critical review of chromatographic procedures since 1992. J. Chromatogr. B. Biomed. Sci. Appl. 1998; 713(1):147–161.
10. Ropero-Miller J.D., Goldberger A., Kone E.J., and Joseph R.E., Jr. The disposition of cocaine and opiate analytes in hair and fingernails of humans following cocaine and codeine administration. J. Anal. Toxicol. 2000; 24(7):496–08.
11. Hubbard D.L., Wilkins D.G., and Rollins D.E., The incorporation of cocaine and metabolites into hair:effects of dose and hair pigmentation. Drug Metab. Dispos. 2000; 28(12):1464–1469.
12. rd International Symposium on Capillary Chromatography, Riva del Garda, Italy, June 5–10, 2000.
13. Brewer W.E., Galipo R.C., Sellers K.W., and Morgan S.L., Analysis of cocaine, benzoylecgonine, codeine, and morphine in hair by supercritical fluid extraction with carbon dioxide modified with methanol. Anal. Chem. 2001; 73(11):2371–2376.
14. Chiarotti M., and Strano-Rossi S., Preparation of hair samples for drug analysis. Forensic Sci. Rev. 1996; 8:112–128.
15. Chiarotti M.and Marsili R., Gas chromatographic analysis of methadone in urine samples after solid phase microextraction. J. Microcolumn Separation. 1994; 6:577–580.
16. Chiarotti M., Strano Rossi S., and Marsili M., Solid-phase microextraction (SPME) and gas-chromatographic analysis of anorectic compounds in human urine. J. Microcolumn Separation. 1997; 9:249–252.
17. Strano Rossi S., and Chiarotti M., Solid-phase microextraction for cannabinoids analysis in hair and its possibile application to other drugs. J. Anal. Toxicol. 1999; 23(1):7–10.
18. Cirimele V., Kintz P., Majdalani R., and Mangin P., Supercritical fluid extraction of drugs in drug addict hair. J. Chromatogr. B. Biomed. Appl. 1995; 673(2):173–181.
19. Morrison J.F., Chesler S.N., Yoo W.J., and Selavka C.M., Matrix and modifier effects in the supercritical fluid extraction of cocaine and benzoylecgonine from human hair. Anal. Chem. 1998; 70(1):163–172.
20. Allen D.L., and Oliver J.S., The application of supercritical fluid extraction in cocaine and its metabolites in blood and urine. J. Anal. Toxicol. 2000; 24(3):228–232.