Insertion of singlet chlorocarbenes across C-H bonds in alkanes: Evidence for two phase mechanism

Journal of Chemical Sciences

Volumn 119, Issue 5, 2007, Pages 467-473

  Ramalingam, M ^a   Ramasami, K ^b   Venuvanalingam, P ^c  

^a Rajah Serfoji Government College Autonomous   (India)

^b NEHRU MEMORIAL COLLEGE   (India)

^c BHARATHIDASAN UNIVERSITY   (India)

Author keywords

C H of alkanes; MP2 and DFT; NBO analysis; Singlet chlorocarbenes insertion

Indexed keywords

CHLOROCARBENES; INSERTION REACTIONS; SINGLET CHLOROCARBENES INSERTION; TRANSITION STATES;

DENSITY FUNCTIONAL THEORY; ETHANE; HYDROGEN BONDS; METHANE; MOLECULAR ORBITALS; REACTION KINETICS;

OLEFINS;

EID: 36849073840     PISSN: 02534134     EISSN: 09737103     Source Type: Journal    
DOI: 10.1007/s12039-007-0060-2     Document Type: Conference Paper

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