Thio-functionalised glucosinolates: unexpected transformation of desulfoglucoraphenin

Tetrahedron Letters

Volumn 49, Issue 2, 2008, Pages 292-295

  Iori, Renato ^a   Barillari, Jessica ^a   Gallienne, Estelle ^b   Bilardo, Cristina ^b   Tatibouët, Arnaud ^b   Rollin, Patrick ^b  

^a ISTITUTO NAZIONALE DELLA NUTRIZIONE   (Italy)

^b UNIVERSITÉ D'ORLÉANS   (France)

Author keywords

Desulfoglucosinolates; Glucosinolates; Thioimidate N oxides; Vinylthio functions

Indexed keywords

DESULFOGLUCORAPHENIN; GLUCOSINOLATE; GLUCOSINOLATE DERIVATIVE; NITRONE DERIVATIVE; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; REACTION ANALYSIS; REVERSED PHASE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

EID: 36849067977     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.11.059     Document Type: Article

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12. 13C δ 150.7 (C-7), 136.5, 135.3 (C-10, C-11), 81.6 (C-1), 81.1 (C-5), 78.2 (C-3), 73.0 (C-2), 69.9 (C-4), 61.1 (C-6), 40.2 (C-12), 30.1 (C-8), 28.5 (C-9).
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23. 13C δ 157.5 (C-7), 84.7 (C-1), 82.2 (C-10), 79.0 (C-5), 74.1 (C-3), 71.2 (C-2), 68.3 (C-4), 62.7 (C-6), 56.7 (C-11), 43.8 (C-12), 32.1 (C-8), 26.3 (C-9).
24. 13C NMR: δ 156.0 (C-7), 87.5 (C-11), 82.8 (C-1), 80.4 (C-5), 77.2 (C-3), 74.6 (C-10), 72.3 (C-2), 69.3 (C-4), 60.8 (C-6), 30.9 (C-8), 17.7 (C-9).
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