메뉴 건너뛰기




Volumn 137, Issue 1-3, 2008, Pages 25-30

Additivity of adiabatic compressibility with the size and geometry of the solute molecule

Author keywords

Adiabatic compressibility coefficients; Hydration; Liquid structure; Non electrolytes in water

Indexed keywords

COMPRESSIBILITY; ELECTROLYTES; GEOMETRY; HYDRATION; SOLUTIONS;

EID: 36549040430     PISSN: 01677322     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molliq.2007.03.001     Document Type: Article
Times cited : (15)

References (46)
  • 1
    • 0017869404 scopus 로고    scopus 로고
    • Probably the first critical review in this matter was J.T. Edsall, H.A. McKenzie, Adv. Biophys. 10 (1978) 137-207. See also the more recent, excellent review: Paulaitis M.E., Garde Sh., Ashbaugh H.S., Curr. Opin. Colloid Interface Sci. 1 (1996) 376-383.
  • 6
    • 36549073335 scopus 로고    scopus 로고
    • See for example H.H. von Emons, Ch. Berger, B. Ponsold, Z. Phys. Chem., Leipzig 256 (1975) 430-435 or G. Oczko, J. Legendziewicz, B. Jeżowska-Trzebiatowska, S. Ernst, Bull. Acad. Pol. Sci., Chem. 28 (1980) 793-800.
  • 7
    • 0035819278 scopus 로고    scopus 로고
    • See for example J. Gliński, B. Keller, J. Legendziewicz, S. Samela, J. Mol. Struct. 559 (2001) 59-66.
  • 8
    • 0001342019 scopus 로고    scopus 로고
    • See for example S. Ernst, B. Jeżowska-Trzebiatowska, J. Phys. Chem. 79 (1975) 2113-2116 (simple electrolytes in mixed solvent water + dioxan).
  • 19
    • 36549007832 scopus 로고    scopus 로고
    • http://www.optel.pl/manual/english/opkud.htm.
  • 21
    • 0141870144 scopus 로고    scopus 로고
    • It is interesting that the shortest compounds fit well to tendencies observed for the series under investigation. This is a very well known observation that in a homologous series, its first member does not fit well to the overall tendency. A good example is water treated as the first member of the series of alcohols. Recently, the same was found for a series of oxyethylenes and their partial molar compressibilities in water changing linearly with the number of oxyethylene units in the molecule, with some exception of the shortest compound: T. Seimiya, J. Colloid Interface Sci. 266 (2003) 422-429.
  • 39
    • 36549076656 scopus 로고    scopus 로고
    • First introduced by J.H. Hildebrand, R.L. Scott, Regular Solutions, Prentice Hall Inc., New Jersey, 1962, further discussed in detail in D.D. MacDonald, J.B. Hyne, Can. J. Chem. 49 (1971) 611-617; D.D. MacDonald, J.B. Hyne, Can. J. Chem. 49 (1971) 2636-2642; M.R.J. Dack, Chem. Soc. Rev. 4 (1975) 211-229.
  • 42
    • 41049110690 scopus 로고    scopus 로고
    • See for example the data for aqueous short-chained normal alcohols: K. Jerie, A. Baranowski, B. Rozenfeld, J. Gliński, S. Ernst, Phys. Scr. 35 (1987) 729-734.
  • 43
    • 36549063910 scopus 로고    scopus 로고
    • See for example our work on the quasichemical model of hydration for tetramethylurea + water system: Gy. Jakli, A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, Bull. Acad. Pol. Sci., Chem. 42 (1994) 67-77.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.