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Volumn 7, Issue 11, 2007, Pages 2262-2264

Highly stable diamondoid network coordination polymer [Mn(NCP) 2]n with notable NLO, magnetic, and luminescence properties

Author keywords

[No Author keywords available]

Indexed keywords


EID: 36549010063     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg070192a     Document Type: Conference Paper
Times cited : (89)

References (29)
  • 16
    • 12044251476 scopus 로고    scopus 로고
    • 1,10-Phenanthroline was oxidized to 1,10-phenanthroline-5,6-dione according to the literature: Hiort, C. Lincoln, P. Norden, B. J. Am. Chem. Soc. 1993, 115, 3448. Preparation of HNCP·2.5H 2O: A mixture of 2 mmol 1,10-phenanthroline-5,6-dione, 2.2mmol 4-carboxybenzaldehyde, 15 mL of glacial acetic acid, and 3.2 g f ammonium acetate in a 100 mL flask with a condenser was refluxed for 2 h, resulting in a yellow precipitate. After cooling, the mixture was diluted with 25 mL of water and the pH value of the solution was adjusted with concentrated aqueous ammonia to 5.5. The yellow product was filtered from the mixture and washed with water and acetone, oven-dried at 60°C (yield: 87% based on 1,10-phenanthroline-5, 6-dione, Mp: 305-307°C Anal. Caled for HNCP·2.5H2O: C, 62.33; H, 4.45; N, 14.54; O, 18.68. Found: C, 62.41; H, 4.38; N, 14.58; O, 18.61. 1H NMR DMSO, 9.05 d 2H, 8.96 d 2H, 8.42 d 2H, 8.19 d 2H, 7.85 dd
    • -1): 3434b, 1615s, 1540m, 1478w, 1451w, 1398s, 1262w, 1071w, 960w, 860w, 838w, 806m, 779w, 732m, 709m.
  • 19
    • 36549027131 scopus 로고    scopus 로고
    • Preparation of [Mn(NCP)2Jn(1, hydrothermal treatment of MnSO4 (0.3 mmol, HNCP·2.5H2O (0.5 mmol) and H2O (25 mL) in an autoclave at 180°C for 3 days gave orange crystals of 1 (yield: 85% based on HNCP, Anal. Caled for Mn 1C40H22N8O4: C, 65.49; H, 3.02; N, 15.27; O, 8.72. Found: C, 65.43; H, 3.06; N, 15.21; O, 8.78. IR (KBr pellet, cm-1, 3435br, 1597s, 1535m, 1475w, 1449w, 1389s, 1274w, 1069m, 948w, 877w, 838w, 806m, 776m, 731m, 717m. Crystal data for compound 1: fw 733.60, orthorhombic, Aba2, a, 15.4071(12) Å, b= 20.450(2) Å, c, 9.9044(10) Å, V, 3120.6(5, Z, 4, ρcalcd, 1.561 g cm-3, p, 0.485 mm-1, R1/wR2, 0.0467/0.1106 (1 > 2σ) and 0.0598/0.1189 (all data, Flack parameter value, 0.043
    • -1, R1/wR2 = 0.0467/0.1106 (1 > 2σ) and 0.0598/0.1189 (all data), Flack parameter value % = 0.04(3).
  • 21
    • 36549044688 scopus 로고    scopus 로고
    • Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Montgomery, J. A. Jr, Vreven, T, Kudin, K. N, Burant, J. C, Millam, J. M, Iyengar, S. S, Tomasi, J, Barone, V, Mennucci, B, Cossi, M, Scalmani, G, Rega, N, Petersson, G. A, Nakatsuji, H, Hada, M, Ehara, M, Toyota, K, Fukuda, R, Hasegawa, J, Ishida, M, Nakajima, T, Honda, Y, Kitao, O, Nakai, H, Klene, M, Li, X, Knox, J. E, Hratchian, H. P, Cross, J. B, Adamo, C, Jaramillo, J, Gomperts, R, tratmann, R. E, Yazyev, S. O, Austin, A. J, Cammi, R, Pomelli, C, Ochterski, J. W, Ayala, P. Y, Morokuma, K, Voth, G. A, Salvador, P, Dannenberg, J. J, Zakrzewski, V. G, Dapprich, S, Daniels, A. D, Strain, M. C, Farkas, O, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Ortiz, J. V, Cui, Q, Baboul, A. G, Clifford, S, Cioslowski, J, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Martin, R. L, Fox, D. J, Keith, T, Al-L
    • Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A. Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Adamo, C.; Jaramillo, J.; Gomperts, R.; tratmann, R. E.; Yazyev, S. O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanaykkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussion 03, Revision A.1; Gaussian, Inc.: Pittsburgh, PA, 2003.


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