NMR structures of peptide-RuII(porphyrin) complexes

Journal of the American Chemical Society

Volumn 129, Issue 46, 2007, Pages 14124-14125

  Wang, Jiangyun ^a   Rosenblatt, Michael M ^a   Suslick, Kenneth S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HEMOPROTEIN; PEPTIDE DERIVATIVE; PORPHYRIN DERIVATIVE; RUTHENIUM COMPLEX;

ARTICLE; CIRCULAR DICHROISM; HYDROPHOBICITY; NUCLEAR MAGNETIC RESONANCE; NUCLEAR OVERHAUSER EFFECT; OXYGEN TRANSPORT; PROTEIN BINDING; PROTEIN FUNCTION; PROTEIN STRUCTURE;

MAGNETIC RESONANCE SPECTROSCOPY; METALLOPORPHYRINS; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; PEPTIDES; RUTHENIUM;

EID: 36448954326     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja075532v     Document Type: Article

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21. Comparisons of our Ru-peptide can be made to structures of heme proteins using the angle defined by the helix axis to the metal center to porphyrin plane: RuAAAXK, 50°; myoglobin, 75°; cytochrome b562, 60°; and cytochrome c peroxidase, 40°. Further discussion is given in the Supporting Information.