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The required intermediate silyl enol ether was generated more selectively by trimethylamine than by other tertiary amines
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The required intermediate silyl enol ether was generated more selectively by trimethylamine than by other tertiary amines.
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19
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2 syn in 1-butene. The former conformation of 1-butene is more stable than the latter by ca. 1.5 kcal/mol; see: Hemelrijk, D. V.; Enden, L. V. D.; Geise, J. J.; Sellers, H. L.; Scafer, L. J. Am. Chem. Soc. 1980, 102, 2189-2194.
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2 syn in 1-butene. The former conformation of 1-butene is more stable than the latter by ca. 1.5 kcal/mol; see: Hemelrijk, D. V.; Enden, L. V. D.; Geise, J. J.; Sellers, H. L.; Scafer, L. J. Am. Chem. Soc. 1980, 102, 2189-2194.
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