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We have assigned the morphology of SI(0.64,1.12)-9 as perforated lamellae (P, however, coexisting lamellae (L) and poorly ordered hexagonally packed cylinders (C) is also a possibility consistent with our scattering results. The PL morphology was predicted by Matsen to remain metastable in polydisperse block copolymer melts as it is in the monodisperse case.29
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ODT represents the average of three measurements during heating scans; the ODT upon cooling occurred slowly and appeared continuous on the experimental time scale (1°C/min).
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ODT represents the average of three measurements during heating scans; the ODT upon cooling occurred slowly and appeared continuous on the experimental time scale (1°C/min).
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PS-PI
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PS-PI
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PS-PI from ref 21 to facilitate comparison with the published PS-PI phase diagram.
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PS-PI from ref 21 to facilitate comparison with the published PS-PI phase diagram.
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A detailed description of the scattering observed in the perforated lamellar phase can be found in: Hamley, I. W.; Castelletto, V.; Mykhaylyk, O. O.; Yang, Z.; May, R.; Lyakhova, K. S.; Sevink, G. J. A.; Zvelindovsky, A. V. Langmuir 2004, 20, 10785.
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A detailed study of its metastability can be found in: Hajduk, D. A.; Takenouchi, H.; Hillmyer, M. A.; Bates, F. S.; Vigild, M. E.; Almdal, K. Macromolecules 1997, 13, 3788.
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Jiang, Y.; Huang, R.; Liang, H. J. Chem Phys. 2005, 123, 124906. The free energy well about the minimum becomes shallower as the PDI is increased. See Figure 10 of ref 6 for another example as calculated by SCFT.
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