Lattice disordering/ordering and demicellization/micellization transitions in highly asymmetric polystyrene-block-polyisoprene copolymers

Macromolecules

Volumn 33, Issue 10, 2000, Pages 3767-3780

  Han, Chang Dae ^a   Vaidya, Nitin Y ^a   Kim, Do ^a   Shin, Gakuji ^b   Yamaguchi, Daisuke ^b   Hashimoto, Takeji ^b  

^a The University of Akron   (United States)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ANIONIC POLYMERIZATION; CRYSTAL LATTICES; MICELLES; MOLECULAR STRUCTURE; ORDER DISORDER TRANSITIONS; POLYISOPRENES; POLYSTYRENES; RHEOLOGY; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; TRANSMISSION ELECTRON MICROSCOPY; X RAY SCATTERING;

DEMICELLIZATION; MICELLIZATION;

BLOCK COPOLYMERS;

EID: 0033744330     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma991862r     Document Type: Article

References (60)

1. (a) Helfand, E.; Wasserman, Z. R. Macromolecules 1976, 9, 879.
2. (b) Helfand, E.; Wasserman, Z. R. Macromolecules 1978, 11, 960.
3. Helfand, E.; Wasserman, Z. R. Macromolecules 1980, 13, 994.
4. Helfand, E.; Wasserman, Z. R. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science: New York, 1982; Chapter 4.
5. Leibler, L. Macromolecules 1980, 13, 1602.
6. Vavasour, J. D.; Whitmore, M. D. Macromolecules 1992, 25, 5477.
7. Matsen, M. W.; Schick, M. Phys. Rev. Lett. 1994, 72, 2660.
8. Hashimoto, T. In Thermoplastic Elastomers; Holden, G., Legge, N. R., Quirk, R, Schroeder, H. E., Eds.; Hanser: Munich, 1996; Chapter 15A.
9. Bates, F. S.; Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990, 41, 525.
10. Han, C. D.; Baek, D. M.; Kim, J. K.; Ogawa, T.; Sakamoto, N.; Hashimoto, T. Macromolecules 1995, 28, 5043.
11. Ogawa, T.; Sakamoto, N.; Hashimoto, T.; Han, C. D.; Baek, D. M. Macromolecules 1996, 29, 2113.
12. Almdal, K.; Koppi, K. A,; Bates, F. S.; Mortensen, K. Macromolecules 1992, 25, 1743.
13. Sakurai, S.; Momii, T.; Taie, K.; Shibayama, M.; Nomura, S.; Hashimoto, T. Macromolecules 1993, 26, 485.
14. Sakurai, S.; Kawada, H.; Hashimoto, T.; Fetters, L. Macromolecules 1993, 26, 5796.
15. Hajduk, D. A.; Gruner, S. M.; Rangarajan, P.; Register, R. S.; Fetters, L. J.; Honeker, C.; Albalak, R. J.; Thomas, E. L. Macromolecules 1994, 27, 490.
16. Hajduk, D. A.; Harper, P. E.; Gruner, S. M.; Honeker, C. C.; Kim, G.; Thomas, E. L.; Fetters, L. J. Macromolecules 1994, 27, 4063.
17. Sakamoto, N.; Hashimoto, T.; Han, C. D.; Kim, D.; Vaidya, N. Y. Macromolecules 1997, 30, 1621.
18. Adams, J. L.; Graessley, W. W.; Register, R. A. Macromolecules 1994, 27, 6026.
19. Adams, J. L.; Quiram, D. J.; Graessley, W. W.; Register, R. A.; Marchand, G. R. Macromolecules 1996, 29, 2929.
20. Sakamoto, N.; Hashimoto, T.; Han, C. D.; Kim, D.; Vaidya, N. Y. Macromolecules 1997, 30, 5321.
21. Schwab, M.; Stühn, B. Colloid Polym. Sci. 1997, 275, 341.
22. Sakamoto, N.; Hashimoto, T. Macromolecules 1998, 31, 8493.
23. Hashimoto, T.; Shibayama, M.; Kawai, H.; Watanabe, H.; Kotaka, T. Macromolecules 1983, 16, 361.
24. Semenov, A. N. Macromolecules 1989, 2, 2849.
25. Matsen, M. W.; Bates, F. S. J. Chem. Phys. 1997, 106, 2436.
26. Kinning, D. J.; Winey, K. I.; Thomas, E. L. Macromolecules 1988, 21, 3502.
27. Kinning, D. J.; Thomas, E. L. J. Chem. Phys. 1988, 90, 5806.
28. Winey, K. I.; Thomas, E. L.; Fetters, L. J. Macromolecules 1992, 25, 2645.
29. Hashimoto, T.; Suehiro, S.; Shibayama, M.; Saijo, K.; Kawai, H. Polym. J. 1981, 13, 501.
30. Suehir, S.; Saijo, K.; Ohta, Y.; Hashimoto, T.; Kawai, H. Anal. Chim. Acta 1986, 189, 41.
31. Fujimura, M.; Hashimoto, T.; Kawai, H. Mem. Fac. Eng., Kyoto Univ. 1981, 43 (2), 224.
32. Hendricks, R. W. J. Appl. Crystallogr. 1972, 5, 315.
33. Gouinlock, E. V.; Porter, R. S. Polym. Eng. Sci. 1977, 17, 535.
34. Chung, C. I.; Lin, M. I. J. Polym. Sci., Polym. Phys. Ed. 1978, 16, 545.
35. Widmaier, J. M.; Meyer, G. C. J. Polym. Sci., Polym. Phys. Ed. 1980, 18, 2217.
36. Rosedale, J. H.; Bates, F. S. Macromolecules 1990, 23, 2329.
37. Bates, F. S.; Rosedale, J. H.; Fredrickson, G. H. J. Chem. Phys. 1990, 92, 6255.
38. Neumann, C.; Loveday, D. R.; Abetz, V.; Stadler, R. Macromolecules 1998, 31, 2493. These authors referred to the logarithmic plot of G′ versus G″ as the Han plot. It is Han and Lem who in 1982 first reported that log G′ versus log G″ plots show temperature independence for homopolymers (ref 36). The Han plot has as its basis a molecular viscoelasticity theory for monodisperse homopolymers (ref 37a) and also for polydisperse homopolymers (ref 37b). Since then, the Han plot has very successfully been used to determine the TODT of microphase-separated block copolymer (ref 38). It should be pointed out that the Han plot has no relation whatsoever to the Cole - Cole plot (ref 39), which gives a temperature-dependent semicircle in rectangular coordinates.
39. Han, C. D.; Lem, K. W. Polym. Eng. Rev. 1982, 2, 135.
40. (a) Han, C. D.; Jhon, M. S. J. Appl. Polym. Sci. 1986, 32, 3809.
41. (b) Han, C. D.; Kim, J. K. Macromolecules 1989, 22, 4292.
42. (a) Han, C. D.; Kim, J. J. Polym. Sci., Polym. Phys. Ed. 1987, 25, 1741.
43. (b) Han, C. D.; Kim, J.; Kim, J. K. Macromolecules 1989, 22, 383.
44. Han, C. D.; Baek, D. M.; Kim, J. K. Macromolecules 1990, 23, 561.
45. Cole, K. S.; Cole, R. H. J. Chem. Phys. 1941, 9, 341.
46. Koga, T.; Koga, T.; Hashimoto, T. J. Chem. Phys. 1999, 110, 11076.
47. Koga, T.; Koga, T.; Hashimoto, T. Phys. Rev. E 1999, 60, R1154.
48. Sakamoto, N.; Hashimoto, T. Macromolecules 1995, 28, 6825.
49. Percus, J. K.; Yevick, G. J. Phys. Rev. 1958, 110, 1.
50. Matsuoka, H.; Tanaka, H.; Hashimoto, T.; Ise, N. Phys. Rev. B 1987, 36, 1754.
51. Matsuoka, H.; Tanaka, H.; Hashimoto, T.; Ise, N. Phys. Rev. B 1990, 41, 3854.
52. Sakamoto, N.; Hashimoto, T. Macromolecules 1995, 28, 6825.
53. Stühn, B.; Mutter, R.; Albrecht, T. Europhys. Lett. 1992, 78, 427.
54. Wolff, T.; Burger, C.; Ruland, W. Macromolecules 1993, 26, 1707.
55. Floudas, G.; Pakula, T.; Fischer, E. W.; Hadiichristidis, N.; Pispas, S. Acta Polym. 1994, 45, 176.
56. Hashimoto, T.; Ogawa, T.; Han, C. D. J. Phys. Soc. Jpn. 1994, 63, 2206.
57. Han, C. D.; Baek, D. M.; Sakurai, S.; Hashimoto, T. Polym. J. 1989, 21, 841.
58. Kasten, H.; Stühn, B. Macromolecules 1995, 28, 4777.
59. Hadjuk, D. A.; Gruner, S. M.; Erramilli, S.; Register, R. A.; Fetters, L. J. Macromolecules 1996, 29, 1473.
60. Floudas, G.; Hadjichristidis, N.; Stamm, M.; Likthman, A. E.; Semenov, A. N. J. Chem. Phys. 1997, 106, 3318.