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Volumn 40, Issue 22, 2007, Pages 7928-7933

Thio-click modification of poly[2-(3-butenyl)-2-oxazoline]

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIVES; COPOLYMERS; ISOMERIZATION; TRANSITION METALS;

EID: 36049017974     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma071357r     Document Type: Article
Times cited : (384)

References (24)
  • 14
    • 36049038647 scopus 로고    scopus 로고
    • MALDI-TOF mass spectrometric analysis of selected poly[2-(3-butenyl)-2- oxazoline]s and modified polymer samples was attempted but failed. Either the signal-to-noise ratio was poor and/or the chains were subject to fragmentation.
    • MALDI-TOF mass spectrometric analysis of selected poly[2-(3-butenyl)-2- oxazoline]s and modified polymer samples was attempted but failed. Either the signal-to-noise ratio was poor and/or the chains were subject to fragmentation.
  • 16
    • 0034009520 scopus 로고    scopus 로고
    • Schuck, P. Biophys. J. 2000, 78, 1606-1619.
    • (2000) Biophys. J , vol.78 , pp. 1606-1619
    • Schuck, P.1
  • 21
    • 36048957959 scopus 로고    scopus 로고
    • The thio-glucose derivative was used in the protected form because it is readily available as such and not because protection of hydroxyl groups would be needed for the free-radical addition onto poly[2-(3-butenyl)-2-oxazoline, A subsequent hydrolysis of the acetyl protecting groups occurs readily by stirring the modified polymer in a mixture of chloroform and 0.5 M sodium methoxide in methanol 9:1 (v/v) for 45 min at room temperature
    • The thio-glucose derivative was used in the protected form because it is readily available as such and not because protection of hydroxyl groups would be needed for the free-radical addition onto poly[2-(3-butenyl)-2-oxazoline]. A subsequent hydrolysis of the acetyl protecting groups occurs readily by stirring the modified polymer in a mixture of chloroform and 0.5 M sodium methoxide in methanol 9:1 (v/v) for 45 min at room temperature.
  • 22
    • 36048949703 scopus 로고    scopus 로고
    • Noticeable amounts of disulfide were not produced during the irradiation of a 4 wt % solution of methyl-3-mercaptopropionate in THF with UV light for 24 h, as shown by GC analysis, even in the absence of poly[2-(3-butenyl)-2- oxazoline].
    • Noticeable amounts of disulfide were not produced during the irradiation of a 4 wt % solution of methyl-3-mercaptopropionate in THF with UV light for 24 h, as shown by GC analysis, even in the absence of poly[2-(3-butenyl)-2- oxazoline].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.