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MALDI-TOF mass spectrometric analysis of selected poly[2-(3-butenyl)-2- oxazoline]s and modified polymer samples was attempted but failed. Either the signal-to-noise ratio was poor and/or the chains were subject to fragmentation.
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MALDI-TOF mass spectrometric analysis of selected poly[2-(3-butenyl)-2- oxazoline]s and modified polymer samples was attempted but failed. Either the signal-to-noise ratio was poor and/or the chains were subject to fragmentation.
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The thio-glucose derivative was used in the protected form because it is readily available as such and not because protection of hydroxyl groups would be needed for the free-radical addition onto poly[2-(3-butenyl)-2-oxazoline, A subsequent hydrolysis of the acetyl protecting groups occurs readily by stirring the modified polymer in a mixture of chloroform and 0.5 M sodium methoxide in methanol 9:1 (v/v) for 45 min at room temperature
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The thio-glucose derivative was used in the protected form because it is readily available as such and not because protection of hydroxyl groups would be needed for the free-radical addition onto poly[2-(3-butenyl)-2-oxazoline]. A subsequent hydrolysis of the acetyl protecting groups occurs readily by stirring the modified polymer in a mixture of chloroform and 0.5 M sodium methoxide in methanol 9:1 (v/v) for 45 min at room temperature.
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22
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36048949703
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Noticeable amounts of disulfide were not produced during the irradiation of a 4 wt % solution of methyl-3-mercaptopropionate in THF with UV light for 24 h, as shown by GC analysis, even in the absence of poly[2-(3-butenyl)-2- oxazoline].
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Noticeable amounts of disulfide were not produced during the irradiation of a 4 wt % solution of methyl-3-mercaptopropionate in THF with UV light for 24 h, as shown by GC analysis, even in the absence of poly[2-(3-butenyl)-2- oxazoline].
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