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In all cases, J1,2 was less than 2.0 Hz, indicating a trans relationship between the substituents at C1 and C2
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1,2 was less than 2.0 Hz, indicating a trans relationship between the substituents at C1 and C2.
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When the β-thioglycoside was used, no reaction was observed, thus demonstrating the need for a trans relationship between the sulfur and the epoxide moiety
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When the β-thioglycoside was used, no reaction was observed, thus demonstrating the need for a trans relationship between the sulfur and the epoxide moiety.
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f's, and separation required acetylation of the mixture followed by chromatography.
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f's, and separation required acetylation of the mixture followed by chromatography.
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