Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks

Journal of the American Chemical Society

Volumn 129, Issue 43, 2007, Pages 12914-12915

  Côté, Adrien P ^a   El Kaderi, Hani M ^a   Furukawa, Hiroyasu ^a   Hunt, Joseph R ^a   Yaghi, Omar M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL COMPOSITION; CONCEPTUAL FRAMEWORK; COVALENT BOND; COVALENT ORGANIC FRAMEWORK; CRYSTAL STRUCTURE; POLYMERIZATION; POROSITY; RETICULAR SYNTHESIS; SOLID STATE; SYNTHESIS; THERMODYNAMICS; THERMOGRAVIMETRY;

EID: 35848931006     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0751781     Document Type: Article

References (17)

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6. 2: C, 74.68; H, 3.13. Found: C, 75.08; H, 3.39.
7. gra and bnn are the three letter designators generally given for important common nets as outlined in Reticular Chemistry Structure Resource (RCSR), http://rcsr.anu.edu.au/.
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10. It is a multiplicity of possibilities in which COF-8 and -12 can stack and pattern where HHTP stack against BTPA/BPBA (turbostratic disorder) which is crystallographically indistinguishable from PXRD/adsorption data; the tailing to high angle of the (100) lines points to translation faults in the xy basal planes. This feature does not preclude nor detract from the application of COFs as porous materials. Due to its large unit cell parameters, the (100) line of COF-10 appears at a very low angle (2θ = 2.8°) and overlaps with scattering from the X-ray source, resulting in an anomalous tailing to low angle of (100) peak and poorer fit of the Le Bail profile in this region (Figure 2).
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