Dzhemilev reaction for the synthesis of spiro[3.3]heptane and spiro[3.4]octanes

Tetrahedron Letters

Volumn 48, Issue 49, 2007, Pages 8583-8586

  D'yakonov, Vladimir A ^a   Finkelshtein, Evgeniy Sh ^b   Ibragimov, Askhat G ^a  

^a INSTITUTE OF PETROCHEMISTRY AND CATALYSIS   (Russian Federation)

^b TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS   (Russian Federation)

Author keywords

6 Thiaspiro 3.4 octane; Catalysis; Cycloalumination; Methylencyclobutane; Organoaluminium compounds; Spiro 3.3 heptane; Spiro 3.4 octane 6 ol

Indexed keywords

6 ETHYL 6 ALUMINASPIRO[3.4]OCTANE; 6 THIASPIRO[3.4]OCTANE; CARBENE; CARBON; CYCLOBUTANE DERIVATIVE; HEPTANE DERIVATIVE; METHYLENECYCLOBUTANE; OCTANE; SPIRO[3.3]HEPTANE; SPIRO[3.4]OCTANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; MASS SPECTROMETRY; METHYLATION; NUCLEAR MAGNETIC RESONANCE; SENSITIVITY ANALYSIS; SYNTHESIS;

EID: 35748958438     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.10.065     Document Type: Article

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29. 2: C, 83.92; H, 12.07; D, 4.01. Found: C, 83.79; H + D 15.93. Yield 92%.
30. 12: C, 87.42; H, 12.58. Found: C, 87.21; H, 12.39. Yield 88%.
31. 12S: C, 65.56; H, 9.43; S, 25.01. Found: C, 65.34; H, 9.21; S, 24.89. Yield 62%.
32. 2: C, 70.10; H, 9.15; O, 20.75. Found: C, 70.02; H, 9.07; O, 20.51.Yield 74%.
33. 14O: C, 76.14; H, 11.18; O, 12.68. Found: C, 76.01; H, 11.13; O, 12.46.Yield 76%.
34. 22: C, 87.56; H, 12.44. Found: C, 87.36; H, 12.18. Yield 81%.