An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes

Chemical Society Reviews

Volumn 25, Issue 6, 1996, Pages 417-426

  Negishi, Ei Ichi ^a   Kondakov, Denis Y ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030327498     PISSN: 03060012     EISSN: None     Source Type: Journal    
DOI: 10.1039/cs9962500417     Document Type: Article

References (8)

1. E. Negishi, 'Organometallics in Organic Synthesis', Wiley-Interscience, New York, 1980, pp. 532.
2. J. P. Collman, L. S. Hegedus, J. R. Norton and R. G. Finke, 'Principles and Applications of Organotransition Metal Chemistry,' University Science Books, Mill Valley, California, 1987.
3. For use of the term 'carbometallation' see (a) D. E. Van Horn and E. Negishi, J. Am. Chem. Soc., 1978, 100, 2252 (b) E. Negishi, Pure Appl. Chem., 1981, 53, 2333 (c) J. F. Normant and A. Alexakis, Synthesis, 1981, 841.
4. For use of the term 'carbometallation' see (a) D. E. Van Horn and E. Negishi, J. Am. Chem. Soc., 1978, 100, 2252 (b) E. Negishi, Pure Appl. Chem., 1981, 53, 2333 (c) J. F. Normant and A. Alexakis, Synthesis, 1981, 841.
5. For use of the term 'carbometallation' see (a) D. E. Van Horn and E. Negishi, J. Am. Chem. Soc., 1978, 100, 2252 (b) E. Negishi, Pure Appl. Chem., 1981, 53, 2333 (c) J. F. Normant and A. Alexakis, Synthesis, 1981, 841.
6. (a) J. Boor, 'Ziegler-Natta Catalysts and Polymerization,' Academic Press, New York, 1978
7. (b) H. Sinn and W. Kaminsky, Adv. Organomet. Chem., 1980, 18, 99.
8. 'Friedel-Crafts and Related Reactions,' ed. G. A. Olah, Interscience Publishers, New York, 1963.